NDLI: 1-Allyl derivatives: Synthesis and crystal structures for [(NH$_{2}$C$_{5}$H$_{4}$N(C$_{3}$H$_{5}$))$_{2}$Cu$_{3}$Cl$_{3}$(NO$_{3}$)$_{2}$] and [C$_{9}$H$_{7}$N(C$_{3}$H$_{5}$)Cu(NO$_{3}$)$

Content Provider	SpringerLink
Author	Pavlyuk, A. V. Lis, T. Mys’kiv, M. G.
Copyright Year	2009
Abstract	1-Allyl-4-aminopyridinium chloride reacts with Cu(NO$_{3}$)$_{2}$ · 3H$_{2}$O in an ethanolic solution under the conditions of ac electrochemical synthesis at copper electrodes to form crystals of compound [(NH$_{2}$C$_{5}$H$_{4}$N(C$_{3}$H$_{5}$))$_{2}$Cu$_{3}$Cl$_{3}$(NO$_{3}$)$_{2}$] (I). The crystals of compound I are monoclinic: space group P2$_{1}$/c, Z = 4, a = 25.770(7), b = 7.230(4), c = 12.505(5) Å, β = 92.58(3)°, V = 2328(2) Å$^{3}$. The direct interaction of 1-allylquinolinium nitrate with Cu(NO$_{3}$)$_{2}$ · 3H$_{2}$O in a methanolic solution in the presence of metallic copper yields crystals of compound [C$_{9}$H$_{7}$N(C$_{3}$H$_{5}$)Cu(NO$_{3}$)$_{2}$] (II). The crystals of compound II are triclinic: space group P $$ \bar 1 $$ , a = 6.756(3), b = 8.391(4), c = 12.489(5) Å, α = 77.18(3)°, β = 89.48(4)°, γ = 73.32(3)°, V = 662.0(5) Å$^{3}$. The structure of compound I is built of infinite linear anions: polymeric fragments {(NH$_{2}$C$_{5}$H$_{4}$N(C$_{3}$H$_{5}$))$_{2}$Cu$_{3}$Cl$_{3}$(NO$_{3}$)$_{2}$}$_{ n }$. Each of two copper atoms (Cu(1) and Cu(2)) π-coordinates the C=C bonds of the allyl groups of the 1-allyl-4-aminopyridinium cations, the oxygen atom of the nitrate ions, and two chlorine atoms. The third copper atom Cu(3) is linearly linked with two chlorine atoms. Particular polymeric fragments are additionally joined by the N-H…O, C-H…O, C-H…Cl hydrogen bonds. The crystal structure of compound II is built-up of the isolated L$_{2}$Cu$_{2}$(NO$_{3}$)$_{4}$ fragments (L is the 1-allylquinolinium cation). The metal atom is localized in the trigonal pyramidal coordination environment of three oxygen atoms of the nitrate ions and of the C=C bond of the allyl group of the cation. The particular L$_{2}$Cu$_{2}$(NO$_{3}$)$_{4}$ fragments are additionally joined by the C-H…O hydrogen bonds.
Starting Page	449
Ending Page	453
Page Count	5
File Format	PDF
ISSN	10703284
Journal	Russian Journal of Coordination Chemistry
Volume Number	35
Issue Number	6
e-ISSN	16083318
Language	English
Publisher	SP MAIK Nauka/Interperiodica
Publisher Date	2009-06-21
Publisher Place	Dordrecht
Access Restriction	Subscribed
Subject Keyword	Inorganic Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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