NDLI: Complexation between N-allylmorpholinium derivatives and copper(I) halides. Synthesis and crystal structure of π-complex {[C$_{4}$H$_{8}$ONH(C$_{3}$H$_{5}$)]$^{+}$}$_{2}$[Cu$_{2}$Cl$

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Complexation between N-allylmorpholinium derivatives and copper(I) halides. Synthesis and crystal structure of π-complex {[C$_{4}$H$_{8}$ONH(C$_{3}$H$_{5}$)]$^{+}$}$_{2}$[Cu$_{2}$Cl$_{4}$]$^{2−}$

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Russian Journal of Coordination Chemistry : Volume 31, Issue 3, March 2005

Russian Journal of Coordination Chemistry : Volume 31, Issue 2, February 2005

Russian Journal of Coordination Chemistry : Volume 31, Issue 1, January 2005

Russian Journal of Coordination Chemistry : Volume 30

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Complexation between N-allylmorpholinium derivatives and copper(I) halides. Synthesis and crystal structure of π-complex {[C$_{4}$H$_{8}$ONH(C$_{3}$H$_{5}$)]$^{+}$}$_{2}$[Cu$_{2}$Cl$_{4}$]$^{2−}$

Content Provider	SpringerLink
Author	Goreshnik, E. A. Davydov, V. N. Mys’kiv, M. G.
Copyright Year	2005
Abstract	Copper(I) π-complex {[C$_{4}$H$_{8}$ONH(C$_{3}$H$_{5}$)]$^{+}$}$_{2}$[Cu$_{2}$Cl$_{4}$]$^{2−}$ (I) was obtained by ac electrochemical synthesis from N-allylmorpholine hydrochloride and copper(II) chloride in ethanol and structurally characterized. In structure I, copper and chlorine atoms form unique noncentrosymmetric Cu$_{2}$Cl 4 2− fragments. Both crystallographically independent N-allylmorpholinium cations are involved in the π-interaction and are coordinated by the copper atom through the C=C bond of the allyl group. The trigonal pyramidal environment of the Cu(1) atom is composed of three chlorine atoms and the C=C bond, while the Cu(2) atom coordinates two chlorine atoms and the C=C bond forming a planar triangle. The extremely strong N-C⋯Cl hydrogen bond (H⋯Cl 2.2 Å) prevents the Cl(1) atom from acting as a bridge and favors the formation of fragments Cu$_{2}$Cl 4 2− .
Starting Page	286
Ending Page	290
Page Count	5
File Format	PDF
ISSN	10703284
Journal	Russian Journal of Coordination Chemistry
Volume Number	31
Issue Number	4
e-ISSN	16083318
Language	English
Publisher	Nauka/Interperiodica
Publisher Date	2005-01-01
Publisher Place	Moscow
Access Restriction	Subscribed
Subject Keyword	Inorganic Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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