NDLI: Synthesis and Crystal Structure of Copper(I) Chloride π-Complexes with N-Allyl- and N,N'-Diallylpiperazinium Dichlorides: [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NH$_{2}$]Cu$_{2}$Cl$_{4}$and [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NHC$_{3}$H$_{5}$]$_{0.5}$CuCl$

Please wait, while we are loading the content...

Solid-Phase Solvate-Free Formation of Magnesium Hydroaluminates Mg(AlH$_{4}$)$_{2}$and MgAlH$_{5}$upon Mechanochemical Activation or Heating of Magnesium Hydride and Aluminum Chloride Mixtures

Synthesis and Structure of Diphenoxytriphenylantimony

Synthesis and Structure of μ-Peroxo-bis(4-bromophenoxotri-p-tolylantimony)

Metal Isotrithionedithiolates as Synthetic Metals

Ionic Strength Dependence of Formation Constants and Complexation of Glutamine with Dioxovanadium(V)

Specific Interaction of Nitrogen(II) Oxide with Sublimed Layers of Iron(II) meso-Mono-4-Pyridyltriphenylporphyrinate

Structure of Tetranuclear Iron(III) d- and dl-Tartrates in Aqueous Solutions

Spin Transitions S= 5/2 ⇄ S= 1/2 in Iron(III) Chelates with Azomethin Ligands

Reactions of Aluminium Tribromide with Tetrakis(triphenylphosphine)nickel(0) and Tetrakis(triethylphosphite)nickel(0) Complexes

K[RuSalphenCl$_{2}$], K[RuSalenCl$_{2}$], and Electroconducting Polymers: Synthesis and Electrochemical Properties

Interaction of Methyl Cysteine and Nitrilotriacetate with Transition Metal Ions

Synthesis and Crystal Structure of Copper(I) Chloride π-Complexes with N-Allyl- and N,N'-Diallylpiperazinium Dichlorides: [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NH$_{2}$]Cu$_{2}$Cl$_{4}$and [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NHC$_{3}$H$_{5}$]$_{0.5}$CuCl$_{2}$

Russian Journal of Coordination Chemistry : Volume 29, Issue 5, May 2003

Russian Journal of Coordination Chemistry : Volume 29, Issue 4, April 2003

Russian Journal of Coordination Chemistry : Volume 29, Issue 3, March 2003

Russian Journal of Coordination Chemistry : Volume 29, Issue 2, February 2003

Russian Journal of Coordination Chemistry : Volume 29, Issue 1, January 2003

Russian Journal of Coordination Chemistry : Volume 28

Russian Journal of Coordination Chemistry : Volume 27

Russian Journal of Coordination Chemistry : Volume 26

Synthesis and Crystal Structure of Copper(I) Chloride π-Complexes with N-Allyl- and N,N'-Diallylpiperazinium Dichlorides: [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NH$_{2}$]Cu$_{2}$Cl$_{4}$and [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NHC$_{3}$H$_{5}$]$_{0.5}$CuCl$_{2}$

Content Provider	SpringerLink
Author	Shkurenko, A. A. Davydov, V. N. Mys'kiv, M. G.
Copyright Year	2003
Abstract	The crystals of copper(I) π-complexes with N-allyl piperazine derivatives, [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NH$_{2}$]Cu$_{2}$Cl$_{4}$(I) and [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NHC$_{3}$H$_{5}$]$_{0.5}$CuCl$_{2}$(II), were prepared by alternating-current electrochemical synthesis. X-ray diffraction study showed that compounds Iand IIcrystallize in the monoclinic system: for I, space group P2$_{1}$/a, a= 10.254(4) Å, b= 12.306(4) Å, c= 10.656(4) Å, γ = 98.83(3)°, V= 1329(2) Å$^{3}$, Z= 4, R= 0.0457 for 1334 independent reflections; for II, space group P2$_{1}$/n, a= 10.187(2) Å, b= 7.283(2) Å, c= 10.480(3) Å, γ = 100.72(2)°, V= 764.0(6) Å$^{3}$, Z= 4, R= 0.0371 for 1025 independent reflections. The structure of Iis composed of {Cu$_{2}$Cl$_{4}$(C$_{7}$H$_{16}$N$_{2}$)}$_{2}$dimers linked by fairly strong (N)H···Cl hydrogen bonds (2.35(4) Å). The structure of IIconsists of centrosymmetrical dimeric Cu$_{2}$Cl$_{4}$ $^{2–}$anions, whose copper atoms coordinate the allyl groups of different centrosymmetrical organic cations. The dimer–ligand chains are stretched along the [ $$ {11} $$ 0] direction and are joined by hydrogen contacts (N)H···Cl (2.62(4) Å).
Starting Page	445
Ending Page	450
Page Count	6
File Format	PDF
ISSN	10703284
Journal	Russian Journal of Coordination Chemistry
Volume Number	29
Issue Number	6
e-ISSN	16083318
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2003-01-01
Publisher Place	New York
Access Restriction	Subscribed
Subject Keyword	Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Libarray of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Unique Isle Anion [Cu$_{6}$Cl$_{10}$]$^{4-}$ in π-Complex of Cu(I) Chloride with 1-(2-Pyridyl)-4-allyl-piperazinium. Synthesis and crystal structure of [(C$_{5}$H$_{4}$NH)NC$_{4}$H$_{8}$NH(C$_{3}$H$_{5}$]$^{2+}$[Cu$_{3}$Cl$_{5}$]$^{2-}$

Cu(I) hexafluorosilicate π-complex with N,N′-diallylpiperazinium, [Cu(H$_{2}$O)$_{2.5}${μ-C$_{4}$H$_{8}$N$_{2}$H$_{2}$(C$_{3}$H$_{5}$)$_{2}$}$_{0.5}$]SiF$_{6}$·H$_{2}$O: Synthesis and crystal structure

1-Allyl derivatives: Synthesis and crystal structures for [(NH$_{2}$C$_{5}$H$_{4}$N(C$_{3}$H$_{5}$))$_{2}$Cu$_{3}$Cl$_{3}$(NO$_{3}$)$_{2}$] and [C$_{9}$H$_{7}$N(C$_{3}$H$_{5}$)Cu(NO$_{3}$)$_{2}$]

Synthesis and crystal structure of π-complex of copper(I) with 1-allylbenzimidazolium cation [C$_{7}$H$_{5}$N$_{2}$H(C$_{3}$H$_{5}$)]$^{+}$ [Cu$_{3}$Cl$_{4}$]$^{−}$

Complexation between N-allylmorpholinium derivatives and copper(I) halides. Synthesis and crystal structure of π-complex {[C$_{4}$H$_{8}$ONH(C$_{3}$H$_{5}$)]$^{+}$}$_{2}$[Cu$_{2}$Cl$_{4}$]$^{2−}$

Synthesis, Spectroscopic Characterization and Crystal Structure of a New Acetyl phosphorylamidate P(O)[NHC(O)C$_{6}$H$_{4}$(4-NO$_{2}$)][N(CH(CH$_{3}$)$_{2}$)(CH$_{2}$C$_{6}$H$_{5}$)]$_{2}$

Synthesis and Crystal Structure of Copper(I) Chloride π-Complexes with N-Allyl- and N,N'-Diallylpiperazinium Dichlorides: [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NH$_{2}$]Cu$_{2}$Cl$_{4}$and [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NHC$_{3}$H$_{5}$]$_{0.5}$CuCl$_{2}$

Similar Documents

Unique Isle Anion [Cu$_{6}$Cl$_{10}$]$^{4-}$ in π-Complex of Cu(I) Chloride with 1-(2-Pyridyl)-4-allyl-piperazinium. Synthesis and crystal structure of [(C$_{5}$H$_{4}$NH)NC$_{4}$H$_{8}$NH(C$_{3}$H$_{5}$]$^{2+}$[Cu$_{3}$Cl$_{5}$]$^{2-}$

Cu(I) hexafluorosilicate π-complex with N,N′-diallylpiperazinium, [Cu(H$_{2}$O)$_{2.5}${μ-C$_{4}$H$_{8}$N$_{2}$H$_{2}$(C$_{3}$H$_{5}$)$_{2}$}$_{0.5}$]SiF$_{6}$·H$_{2}$O: Synthesis and crystal structure

1-Allyl derivatives: Synthesis and crystal structures for [(NH$_{2}$C$_{5}$H$_{4}$N(C$_{3}$H$_{5}$))$_{2}$Cu$_{3}$Cl$_{3}$(NO$_{3}$)$_{2}$] and [C$_{9}$H$_{7}$N(C$_{3}$H$_{5}$)Cu(NO$_{3}$)$_{2}$]

Synthesis and crystal structure of π-complex of copper(I) with 1-allylbenzimidazolium cation [C$_{7}$H$_{5}$N$_{2}$H(C$_{3}$H$_{5}$)]$^{+}$ [Cu$_{3}$Cl$_{4}$]$^{−}$

Complexation between N-allylmorpholinium derivatives and copper(I) halides. Synthesis and crystal structure of π-complex {[C$_{4}$H$_{8}$ONH(C$_{3}$H$_{5}$)]$^{+}$}$_{2}$[Cu$_{2}$Cl$_{4}$]$^{2−}$

Synthesis, Spectroscopic Characterization and Crystal Structure of a New Acetyl phosphorylamidate P(O)[NHC(O)C$_{6}$H$_{4}$(4-NO$_{2}$)][N(CH(CH$_{3}$)$_{2}$)(CH$_{2}$C$_{6}$H$_{5}$)]$_{2}$

Synthesis and Crystal Structure of Copper(I) Chloride π-Complexes with N-Allyl- and N,N'-Diallylpiperazinium Dichlorides: [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NH$_{2}$]Cu$_{2}$Cl$_{4}$and [C$_{3}$H$_{5}$NH(CH$_{2}$)$_{4}$NHC$_{3}$H$_{5}$]$_{0.5}$CuCl$_{2}$