NDLI: 1,3-Bis(4-Pyridinylcarbonyl)-2-Imidazolidinethione and Its First Cluster Complex: Synthesis, Crystal Structure and Luminescence Properties

Content Provider	SpringerLink
Author	Wang, Qingli Li, Jinpeng Sun, Dong Hou, Hongwei Zhang, Hongyun Niu, Yunyin Xu, Na
Copyright Year	2008
Abstract	The first cluster complex of 1,3-bis(4-pyridinylcarbonyl)-2-imidazolidinethione (4-bpit) with CuI was prepared and characterized. Single crystal X-ray diffraction analysis established that the compound crystallizes in the monoclinic system, space group C2/m, with a = 15.601(3), b = 12.438(3), c = 12.570(3)Å, β = 110.02(3), Z = 4, V = 2291.8(8)Å$^{3}$. This compound is also a coordination polymer with one-dimensional double-ribbon structure containing the adaptable rhomboid Cu$_{2}$I$_{2}$ cluster unit. The solution-state luminescence spectra showed that the high-energy emission may be associated with a ligand-to-ligand charge-transfer excited state.The first cluster complex of 1,3-bis(4-pyridinylcarbonyl)-2-imidazolidinethione (4-bpit) with CuI was prepared and characterized. This compound is also a coordination polymer with one-dimensional double-ribbon structure containing the adaptable rhomboid Cu$_{2}$I$_{2}$ cluster unit. The solution-state luminescence spectra showed that the high-energy emission may be associated with a ligand-to-ligand charge-transfer excited state.
Starting Page	42
Ending Page	45
Page Count	4
File Format	PDF
ISSN	10741542
Journal	Journal of Chemical Crystallography
Volume Number	39
Issue Number	1
e-ISSN	15728854
Language	English
Publisher	Springer US
Publisher Date	2008-06-19
Publisher Place	Boston
Access Restriction	Subscribed
Subject Keyword	Coordination polymer Cluster complex Crystal structure Inorganic Chemistry Physical Chemistry Crystallography Organometallic Chemistry
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics Chemistry

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