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A new hetero-bimetallic coordination polymer, cesium, and sodium complex of styphnate trihydrate [CsNa(TNR)(H$_{2}$O)$_{3}$]$_{ n }$

Content Provider	SpringerLink
Author	Liu, Jun Wei Zhang, Jian Guo Zhang, Tong Lai Zheng, Hong Yang, Li Yu, Kai Bei
Copyright Year	2009
Abstract	A new hetero-bimetallic coordination polymer, cesium, and sodium complex of styphnate trihydrate [CsNa(TNR)(H$_{2}$O)$_{3}$]$_{ n }$ (TNR: 2,4,6-trinitroresorcinol dianion, the dianion of styphnic acid) was synthesized. The title complex was characterized by X-ray single crystal diffraction, element analysis, FT-IR, DSC, TG-DTG studies. In the title polymer molecule, the cesium cation is coordinated by 13 oxygen atoms: three originated from the water molecule and the others are from the nitro group and the phenolic hydroxyl group of TNR; the sodium cation is surrounded by six oxygen atoms from water molecules and TNR forming a distorted octahedron. The coordination polymer crystal was formed by the bridging ligands of water molecules and TNR connected with different cesium and sodium cations.
Starting Page	387
Ending Page	392
Page Count	6
File Format	PDF
ISSN	10400400
Journal	Structural Chemistry
Volume Number	20
Issue Number	3
e-ISSN	15729001
Language	English
Publisher	Springer US
Publisher Date	2009-02-12
Publisher Place	Boston
Access Restriction	Subscribed
Subject Keyword	Hetero-bimetallic coordination polymer Cesium complex Sodium complex Styphnic acid Crystal structure Theoretical and Computational Chemistry Physical Chemistry Computer Applications in Chemistry
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics Physical and Theoretical Chemistry

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