NDLI: Synthesis, crystal structure, and properties of a three-dimensional coordination polymer [Cd(PMP)$_{2}$]$

Content Provider	SpringerLink
Author	Xu, Rui Bo Xu, Xing You Li, Shu An Wang, Ming Yan Yang, Xu Jie Wang, Da Qi Huang, Yu Ping Xu, Chun Mei
Copyright Year	2010
Abstract	A new Cd(II) coordination polymer, [Cd(PMP)$_{2}$]$_{n}$ (1) [PMP = 1-phenyl-3-methyl-5-pyrazolone], has been synthesized by the reaction of Cd(CH$_{3}$COO)$_{2}$·2H$_{2}$O with PMP and characterized by elemental analysis, IR spectrum, fluorescence spectrum, UV–vis spectrum, TG–DTA, and electrochemical analysis. Single crystal X-ray diffraction reveals that the complex has a three-dimensional network. Each PMP acts as bidentate bridging ligand and each Cd(II) center is surrounded by two O atoms and two N atoms from four different PMP ligands to form distorted tetrahedral coordination geometry. The photoluminescence study shows the complex exhibited strong solid state blue fluorescent emission at room temperature, and the TG–DTA analysis demonstrated that it has highly thermal stability. Furthermore, the electrochemical property of the complex has been investigated for the first time in DMF by cyclic voltammetry, and the results showed that it has an irreversible process.
Starting Page	1085
Ending Page	1091
Page Count	7
File Format	PDF
ISSN	10400400
Journal	Structural Chemistry
Volume Number	21
Issue Number	5
e-ISSN	15729001
Language	English
Publisher	Springer US
Publisher Date	2010-07-27
Publisher Place	Boston
Access Restriction	Subscribed
Subject Keyword	Coordination polymer Crystal structure 1-phenyl-3-methyl-5-pyrazolone Fluorescence Thermal stability Cyclic voltammetry Theoretical and Computational Chemistry Physical Chemistry Computer Applications in Chemistry
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics Physical and Theoretical Chemistry

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