NDLI: Subsolidus binary phase diagram of the bilayer compounds [n-C$_{ n }$H$_{2n+1}$N(CH$_{3}$)$_{3}$]$_{2}$ZnCl$

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Subsolidus binary phase diagram of the bilayer compounds [n-C$_{ n }$H$_{2n+1}$N(CH$_{3}$)$_{3}$]$_{2}$ZnCl$_{4}$ (n = 16, 18)

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Subsolidus binary phase diagram of the bilayer compounds [n-C$_{ n }$H$_{2n+1}$N(CH$_{3}$)$_{3}$]$_{2}$ZnCl$_{4}$ (n = 16, 18)

Content Provider	SpringerLink
Author	Ruan, Bei Wu, KeZhong Chen, Jing Xiong, YuanYuan Ren, BiYan
Copyright Year	2014
Abstract	The bilayer compounds [n-C$_{ n }$H$_{2n+1}$N(CH$_{3}$)$_{3}$]$_{2}$ZnCl$_{4}$ (n = 16, 18) experience solid-solid phase transition within the temperature range of 310 to 340 K. The low-temperature crystal structures of the pure compounds are characteristic of the piling effect in which a 2D macro-anion ZnCl$_{4}$ $^{2−}$ is sandwiched between two alkylammonium layers. These layers become conformationally disordered in the high-temperature phases. The structures can alternatively be viewed as a double layer of alkylammonium ions between ZnCl$_{4}$ $^{2−}$ sheets and can be considered as crystalline models of lipid bilayers. The experimental subsolidus binary phase diagram of [n-C$_{16}$H$_{33}$N(CH$_{3}$)$_{3}$]$_{2}$ZnCl$_{4}$-[n-C$_{18}$H$_{37}$N(CH$_{3}$)$_{3}$]$_{2}$ZnCl$_{4}$ has also been established over the whole composition range by differential scanning calorimetry (DSC) and X-ray diffraction. In the phase diagram, one intermediate compound [n-C$_{16}$H$_{33}$N(CH$_{3}$)$_{3}$][n-C$_{18}$H$_{37}$N(CH$_{3}$)$_{3}$]ZnCl$_{4}$ at $$W_{C_{16} C_3 Zn} \%$$ 47.50 and two eutectoid invariants points at $$W_{C_{16} C_3 Zn} \%$$ 35.10 and 75.70 were observed; the respective temperatures of the two eutectoids are 320 ± 1 and 315 ± 1 K. In addition, there are three noticeable solid solution ranges in the phase diagram: α-phase at the left, β-phase at the right, and γ-phase in the middle.
Starting Page	1703
Ending Page	1707
Page Count	5
File Format	PDF
ISSN	16747291
Journal	Science in China Series B: Chemistry
Volume Number	57
Issue Number	12
e-ISSN	18691870
Language	English
Publisher	Science China Press
Publisher Date	2014-11-03
Publisher Place	Heidelberg
Access Restriction	Subscribed
Subject Keyword	lipid bilayers n-hexadecyltrimethylammonium tetrachlorozincate n-trimethylstearylammonium tetrachlorozincate phase transitions phase diagram Chemistry/Food Science
Content Type	Text
Resource Type	Article
Subject	Chemistry

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Subsolidus binary phase diagram of the bilayer compounds [n-C$_{ n }$H$_{2n+1}$N(CH$_{3}$)$_{3}$]$_{2}$ZnCl$_{4}$ (n = 16, 18)

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