NDLI: Ruthenium(II) 2,2′-bipyridine complexes incorporating substituted phenylazo-(2-(phenylthio))phenylmethine ancillary ligands. Synthesis, crystal structure, spectroscopic and redox properties

Content Provider	SpringerLink
Author	Al aimi, Mousa El khateeb, Mohammad Haddad, Salim F. Saadeh, Haytham
Copyright Year	2010
Abstract	Five ruthenium complexes bearing phenylazo-(2-(phenylthio))phenylmethine ligands of the general type trans-[Ru$^{II}$(bpy)(L)(Cl)$_{2}$] (C1–C5) {L = YC$_{6}$H$_{4}$N=NC(COCH$_{3}$)=NC$_{6}$H$_{4}$(2-SC$_{6}$H$_{5}$), H (L1), Cl (L2), OCH$_{3}$ (L3), Br (L4), or NO$_{2}$ (L5)} have been synthesized. The crystal structure of trans-[Ru(bpy)(L1)(Cl)$_{2}$] (C1) is reported and shows no direct metal–S interaction. The complexes have been characterized through spectroscopic (IR, UV/vis and NMR) and electrochemical (CV) techniques. The electrochemical parameters (E $_{L}$(L)) of the azoimine ligands are reported.Five ruthenium complexes bearing phenylazo-(2-(phenylthio))phenylmethine ligands of the general type trans-[Ru$^{II}$(bpy)(L)(Cl)$_{2}$] {L = YC$_{6}$H$_{4}$N=NC(COCH$_{3}$)=NC$_{6}$H$_{4}$(2-SC$_{6}$H$_{5}$), Y = H (L1), Cl (L2), OCH$_{3}$ (L3), Br (L4), and NO$_{2}$ (L5)} has been synthesized. The crystal structure of the complex trans-[Ru(bpy)(L1)(Cl)$_{2}$] is reported and show no direct metal–S interactions. This family has been characterized through spectroscopic and electrochemical techniques. The electrochemical parameters (E $_{L}$(L)) of these new ligands (L) are reported.
Starting Page	877
Ending Page	883
Page Count	7
File Format	PDF
ISSN	03404285
Journal	Transition Metal Chemistry
Volume Number	35
Issue Number	7
e-ISSN	1572901X
Language	English
Publisher	Springer Netherlands
Publisher Date	2010-08-13
Publisher Place	Dordrecht
Access Restriction	Subscribed
Subject Keyword	Inorganic Chemistry Physical Chemistry Catalysis
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry Materials Chemistry Metals and Alloys

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