NDLI: Synthesis, crystal structures and photocatalytic properties of Zn(II), Ni(II), Co(II) complexes with a symmetric open-chain N$_{2}$O$

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Synthesis, crystal structures and photocatalytic properties of Zn(II), Ni(II), Co(II) complexes with a symmetric open-chain N$_{2}$O$_{4}$-donor bis-Schiff base ligand

Content Provider	SpringerLink
Author	Wang, Hu Zhang, Xiao Yin Bi, Cai Feng Fan, Yu Hua Meng, Xiang Min
Copyright Year	2015
Abstract	Three complexes, Zn(C$_{40}$H$_{36}$N$_{4}$O$_{8}$)·3CH$_{3}$OH (1), Ni(C$_{40}$H$_{36}$N$_{4}$O$_{8}$)·3CH$_{3}$OH (2) and Co(C$_{40}$H$_{36}$N$_{4}$O$_{8}$)·3CH$_{3}$OH (3), with a sexidentate (N$_{2}$O$_{4}$) symmetric bis-Schiff base ligand (C$_{40}$H$_{36}$N$_{4}$O$_{8}$ = 1,2-bis(2-methoxy-6-formylphenoxy)ethane-l-tryptophan) have been synthesized and characterized by physicochemical and spectroscopic methods. The X-ray crystal structures show that the metal atoms of three complexes are all six-coordinated by two nitrogens from C=N groups, two oxygens from ether groups and two carboxylic oxygens in the mono-ligand, forming a distorted octahedral geometry. The complexes were screened as photocatalysts for the degradation of methylene blue, rhodamine B and methyl violet. All three complexes proved to be good candidates for the photocatalytic degradation of methylene blue and complexes 2–3 are also good photocatalysts for the degradation of rhodamine B. The mechanism of these photocatalytic degradations is discussed.The main characterization and photocatalytic experiment of three complexes.
Starting Page	769
Ending Page	777
Page Count	9
File Format	PDF
ISSN	03404285
Journal	Transition Metal Chemistry
Volume Number	40
Issue Number	7
e-ISSN	1572901X
Language	English
Publisher	Springer International Publishing
Publisher Date	2015-09-05
Publisher Place	Cham
Access Restriction	Subscribed
Subject Keyword	Catalysis Physical Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry Materials Chemistry Metals and Alloys

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Synthesis, crystal structures and photocatalytic properties of Zn(II), Ni(II), Co(II) complexes with a symmetric open-chain N$_{2}$O$_{4}$-donor bis-Schiff base ligand

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