NDLI: Molar heat capacity and thermodynamic properties of crystalline [Nd(Glu)(H$_{2}$O)$_{5}$(Im)$_{3}$](ClO$_{4}$)$_{6}$·2H$

Content Provider	SpringerLink
Author	Lv, X. C. Tan, Z. C. Gao, X. H. Shi, Q. Sun, L. X.
Copyright Year	2009
Abstract	A complex of neodymium perchloric acid coordinated with L-glutamic acid and imidazole, [Nd(Glu)(H$_{2}$O)$_{5}$(Im)$_{3}$](ClO$_{4}$)$_{6}$·2H$_{2}$O was synthesized and characterized by IR and elements analysis for the first time. The thermodynamic properties of the complex were studied with an automatic adiabatic calorimeter and differential scanning calorimetry (DSC). Glass transition and phase transition were discovered at 221.83 and 245.45 K, respectively. The glass transition was interpreted as a freezing-in phenomenon of the reorientational motion of ClO 4 − ions and the phase transition was attributed to the orientational order/disorder process of ClO 4 − ions. The heat capacities of the complex were measured with the automatic adiabatic calorimeter and the thermodynamic functions [H $_{T}$-H $_{298.15}$] and [S $_{T}$-S $_{298.15}$] were derived in the temperature range from 80 to 390 K with temperature interval of 5 K. Thermal decomposition behavior of the complex in nitrogen atmosphere was studied by thermogravimetric (TG) analysis and differential scanning calorimetry (DSC).
Starting Page	387
Ending Page	392
Page Count	6
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	95
Issue Number	2
e-ISSN	15728943
Language	English
Publisher	Springer Netherlands
Publisher Date	2009-03-12
Publisher Place	Dordrecht
Access Restriction	Subscribed
Subject Keyword	adiabatic calorimetry glass transition low-temperature heat capacity [Nd(Glu)(H$_{2}$O)$_{5}$(Im)$_{3}$](ClO$_{4}$)$_{6}$·2H$_{2}$O phase transition thermal analysis Measurement Science, Instrumentation Inorganic Chemistry Polymer Sciences Analytical Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics Physical and Theoretical Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Libarray of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Thermodynamic properties and molar heat capacity of Er$_{2}$(Asp)$_{2}$(Im)$_{8}$(ClO$_{4}$)$_{6}$·10H$_{2}$O

Molar heat capacity and thermodynamic properties of Lu(C$_{5}$H$_{9}$NO$_{4}$)(C$_{3}$H$_{4}$N$_{2}$)$_{6}$(ClO$_{4}$)$_{3}$·5HClO$_{4}$·10H$_{2}$O

Molar heat capacity and thermodynamic properties of crystalline Eu(C$_{2}$H$_{5}$O$_{2}$N)$_{2}$Cl$_{3}$·3H$_{2}$O

Low-temperature molar heat capacities and thermodynamic properties of a new rare earth complex Er$_{2}$(μ $_{2}$-Gly)$_{6}$(H$_{2}$O)$_{4}$·Na$_{2}$(ClO$_{4}$)$_{8}$(H$_{2}$O)$_{2}$·4H$_{2}$O

Heat capacity and thermodynamical properties of the crystal of [RE$_{2}$(Glu)$_{2}$(H$_{2}$O)$_{8}$](ClO$_{4}$)$_{4}$·H$_{2}$O (RE = Nd, Eu, Dy)

Low-temperature heat capacity and standard enthalpy of formation of neodymium glycine perchlorate complex [Nd$_{2}$(Gly)$_{6}$(H$_{2}$O)$_{4}$](ClO$_{4}$)$_{6}$·5H$_{2}$O

Molar heat capacity and thermodynamic properties of crystalline Ho(Asp)Cl$_{2}$·6H$_{2}$O

Molar heat capacity and thermodynamic properties of 1,2-cyclohexane dicarboxylic anhydride [C$_{8}$H$_{10}$O$_{3}$]

Thermodynamic properties of LiZr$_{2}$(PO$_{4}$)$_{3}$ crystal phosphate

Molar heat capacity and thermodynamic properties of crystalline [Nd(Glu)(H$_{2}$O)$_{5}$(Im)$_{3}$](ClO$_{4}$)$_{6}$·2H$_{2}$O

Similar Documents

Thermodynamic properties and molar heat capacity of Er$_{2}$(Asp)$_{2}$(Im)$_{8}$(ClO$_{4}$)$_{6}$·10H$_{2}$O

Molar heat capacity and thermodynamic properties of Lu(C$_{5}$H$_{9}$NO$_{4}$)(C$_{3}$H$_{4}$N$_{2}$)$_{6}$(ClO$_{4}$)$_{3}$·5HClO$_{4}$·10H$_{2}$O

Molar heat capacity and thermodynamic properties of crystalline Eu(C$_{2}$H$_{5}$O$_{2}$N)$_{2}$Cl$_{3}$·3H$_{2}$O

Low-temperature molar heat capacities and thermodynamic properties of a new rare earth complex Er$_{2}$(μ $_{2}$-Gly)$_{6}$(H$_{2}$O)$_{4}$·Na$_{2}$(ClO$_{4}$)$_{8}$(H$_{2}$O)$_{2}$·4H$_{2}$O

Heat capacity and thermodynamical properties of the crystal of [RE$_{2}$(Glu)$_{2}$(H$_{2}$O)$_{8}$](ClO$_{4}$)$_{4}$·H$_{2}$O (RE = Nd, Eu, Dy)

Low-temperature heat capacity and standard enthalpy of formation of neodymium glycine perchlorate complex [Nd$_{2}$(Gly)$_{6}$(H$_{2}$O)$_{4}$](ClO$_{4}$)$_{6}$·5H$_{2}$O

Molar heat capacity and thermodynamic properties of crystalline Ho(Asp)Cl$_{2}$·6H$_{2}$O

Molar heat capacity and thermodynamic properties of 1,2-cyclohexane dicarboxylic anhydride [C$_{8}$H$_{10}$O$_{3}$]

Thermodynamic properties of LiZr$_{2}$(PO$_{4}$)$_{3}$ crystal phosphate

Molar heat capacity and thermodynamic properties of crystalline [Nd(Glu)(H$_{2}$O)$_{5}$(Im)$_{3}$](ClO$_{4}$)$_{6}$·2H$_{2}$O