NDLI: Crystal structures of trans-dichlorobis(ethylendiamine) rhodium(III) with univalent anions

Content Provider	SpringerLink
Author	Baidina, I. A. Vorob’eva, S. N. Smolentsev, A. I. Belyaev, A. V.
Copyright Year	2011
Abstract	The crystal structures of the compounds trans-[Rh(en)$_{2}$Cl$_{2}$]Cl$_{2}$ · H$_{5}$O$_{2}$ (I), trans-[Rh(en)$_{2}$Cl$_{2}$]ClO$_{4}$ (II), and trans-[Rh(en)$_{2}$Cl$_{2}$]ReO$_{4}$ (III) are determined. The crystal data are: I, a = 10.860(3) Å, b = 7.795(2) Å, c = 9.023(3) Å; β = 111.56(10)°, P2$_{1}$/c space group, Z = 4, d $_{x}$ = 1.875 g/cm$^{3}$; II, a = 6.593(2) Å, b = 8.309(3) Å, c = 11.922(4) Å, α = 83.55(10)°, β = 79.80(10)°, γ = 75.38(10)°, P $$ \bar 1 $$ space group, Z = 2, d $_{x}$ = 2.106 g/cm$^{3}$; III, a = 6.533(2) Å, b = 16.391(4) Å, c = 12.411(3) Å; β = 98.30(10)°, P2$_{1}$/c space group, Z = 4, d $_{x}$ = 2.749 g/cm$^{3}$. The compounds are examined by IR spectroscopy and powder XRD. The solubility of the isolated crystalline phases in water decreases in the following order: trans-[Rh(en)$_{2}$Cl$_{2}$]Cl$_{2}$·H$_{5}$O$_{2}$ > trans-[Rh(en)$_{2}$Cl$_{2}$]ClO$_{4}$ > trans-[Rh(en)$_{2}$Cl$_{2}$]ReO$_{4}$.
Starting Page	133
Ending Page	139
Page Count	7
File Format	PDF
ISSN	00224766
Journal	Journal of Structural Chemistry
Volume Number	52
Issue Number	1
e-ISSN	15738779
Language	English
Publisher	SP MAIK Nauka/Interperiodica
Publisher Date	2011-03-31
Publisher Place	Dordrecht
Access Restriction	Subscribed
Subject Keyword	rhodium trans-tetramines coordination compounds crystal structure Atomic, Molecular, Optical and Plasma Physics Physical Chemistry Atomic/Molecular Structure and Spectra Solid State Physics Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Inorganic Chemistry Physical and Theoretical Chemistry

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