NDLI: Crystal structures of cobalt(II) complexes with N-(2-hydroxyethyl)iminodiacetic and N,N-bis(2-carbamoylethyl)aminoacetic acids: Co(Heida)·2H$_{2}$O and Co(Bcegly)(ClO$_{4}$)·2H$

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Crystal structures of cobalt(II) complexes with N-(2-hydroxyethyl)iminodiacetic and N,N-bis(2-carbamoylethyl)aminoacetic acids: Co(Heida)·2H$_{2}$O and Co(Bcegly)(ClO$_{4}$)·2H$_{2}$O

Content Provider	SpringerLink
Author	Zabel, M. Poznyak, A. L. Pavlovskii, V. I.
Copyright Year	2006
Abstract	The cobalt atom in the structures studied is situated in the center of an octahedron involving donor atoms N and 3O organic ligands Heida or Bcegly (ions of hydroxyethyliminodiacetate or bis(carbamoylethyl)aminoacetate, respectively), water molecule oxygen atom, and a carboxylic atom of the neighboring ligand in the trans-position to the N atom, so that each (II) ion is linked with two organic anions. This results in a formation of infinite chains — uncharged [Co(Heida)(H$_{2}$O)]$_{n}$ or cationic {[Co(Bcegly)(H$_{2}$O)]$^{+}$}$_{n}$. In both cases, a molecule of crystallization water is present, and in the second case, the charge of the chains is compensated by perchlorate ions. Aminoacetic cycle of the Heida ligand is approximately coplanar to another such cycle, while a similar cycle of the Bcegly ligand is in the plane of one of six-membered aminopropionamide cycles.
Starting Page	989
Ending Page	993
Page Count	5
File Format	PDF
ISSN	00224766
Journal	Journal of Structural Chemistry
Volume Number	47
Issue Number	5
e-ISSN	15738779
Language	English
Publisher	Kluwer Academic Publishers-Consultants Bureau
Publisher Date	2006-01-01
Publisher Place	New York
Access Restriction	Subscribed
Subject Keyword	crystal structure N-(2-hydroxyethyl)iminodiacetatocobalt(II) N,N-bis(2-carbamoyl)aminoacetatocobalt(II) Inorganic Chemistry Physical Chemistry Atoms, Molecules, Clusters and Plasmas Atomic and Molecular Structure and Spectra Solid State Physics and Spectroscopy
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Inorganic Chemistry Physical and Theoretical Chemistry

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Crystal and molecular structure of [N,N-bis(2-carbamoylethyl)aminoacetato](imidazole)copper(II) perchlorate monohydrate, [Cu(Bcegly)(Im)](ClO$_{4}$) · H$_{2}$O

Crystal structure of barium bis[N-(2-hydroxyethyl)iminodiacetato]cobaltate(III) hydrocarbonate dihydrate Ba(μ$_{4}$-HCO$_{3}$)[trans(N)-Co(heida)$_{2}$]·2H$_{2}$O

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Triethylenetetramine(3-sulfinatopropanoato-O,S)cobalt(III) isomers: Synthesis and structure of α-cis-[Co(Trien)(O$_{2}$CC$_{2}$H$_{4}$SO$_{2}$)]ClO$_{4}$ · 2H$_{2}$O and β-cis-[Co(Trien)(O$_{2}$CC$_{2}$H$_{4}$SO$_{2}$)]ClO$_{4}$

Crystal structure of N-(2-hydroxyethyl)-β-alanine and racemic mixture of the coordination stereoisomers of N-(2-hydroxyethyl)-β-alaninatonickel(II)

Copper(II) complexes with N-(2-hydroxyethyl)-2-iminodiacetic acid and imidazoles: crystal structure, spectroscopic studies and superoxide dismutase activity

Crystal structure of bis(2,2′-bipyridyl-N,N′)-(2,2′-diphenyldicarboxylato- O,O′)cobalt(II) dihydrate, Co(C10H8N2)2(C14H8O4) · 2H2O

27Al NMR studies on complexation of aluminium with N-(2’-hydroxyethyl)iminodiacetic acid, N,N,-bis(2'-hydroxyethyl)glycine and triethanolamine

Crystal structures of cobalt(II) complexes with N-(2-hydroxyethyl)iminodiacetic and N,N-bis(2-carbamoylethyl)aminoacetic acids: Co(Heida)·2H$_{2}$O and Co(Bcegly)(ClO$_{4}$)·2H$_{2}$O

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