NDLI: Synthesis of β‐Chlorinated Macrocyclic [Au(C$_{14}$H$_{20}$N$_{4}$Cl$_{2}$)]X (X = AuCl$_{2}$, ClO$_{4}$, AuCl$_{4}$) Gold(III) Complexes. Crystal and Molecular Structures of [Au(C$_{14}$H$_{20}$N$_{4}$Cl$_{2}$)]ClO$

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Synthesis of β‐Chlorinated Macrocyclic [Au(C$_{14}$H$_{20}$N$_{4}$Cl$_{2}$)]X (X = AuCl$_{2}$, ClO$_{4}$, AuCl$_{4}$) Gold(III) Complexes. Crystal and Molecular Structures of [Au(C$_{14}$H$_{20}$N$_{4}$Cl$_{2}$)]ClO$_{4}$

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Synthesis of β‐Chlorinated Macrocyclic [Au(C$_{14}$H$_{20}$N$_{4}$Cl$_{2}$)]X (X = AuCl$_{2}$, ClO$_{4}$, AuCl$_{4}$) Gold(III) Complexes. Crystal and Molecular Structures of [Au(C$_{14}$H$_{20}$N$_{4}$Cl$_{2}$)]ClO$_{4}$

Content Provider	SpringerLink
Author	Afanas'eva, V. A. Glinskaya, L. A. Klevtsova, R. F. Mirov, I. V. Sheludyakova, L. A. Tkachev, S. V.
Copyright Year	2003
Abstract	A square‐planar [AuL$_{2}$]$^{+}$ gold(III) complex [L$_{2}$ = 6.13‐dichloro‐5,7,12,14‐tetramethyl‐1,4,8,11‐tetraaza‐4,6,11,13‐tetraenato(2-)] containing two chlorine atoms in the β‐position of the ligand hexacyclic ring was first synthesized by the reaction of the [AuL$_{1}$]$^{+}$ tetraiminate complex [L$_{1}$ = 5,7,12,14‐tetramethyl‐1,4,8,11‐tetraaza‐4,6,11,13‐tetraenato(2-)] with HAuCl$_{4}$ in an acetone – DMFA solution. The complex was isolated in the form of dichloroaurite (I), perchlorate (II), and tetrachloroaurate (III). Compounds I–III were studied by elemental and X‐ray diffraction analyses and IR and NMR spectroscopies. Single crystals of [AuL$_{2}$]ClO$_{4}$ were obtained, and the crystal structure of this compound was determined from X‐ray diffraction patterns. The crystals are monoclinic: a = 10.147(2)Å, b = 7.260(1)Å, c = 12.519(2)Å, β = 96.70(1)°, V = 915.9(3)Å$^{3}$, Z = 2, space group P2/c, d$_{calc}$ = 2.218, d$_{meas}$ = 2.209 g/cm$^{3}$ The crystal structure is built of nearly planar [Au(C$_{14}$H$_{20}$N$_{4}$Cl$_{2}$)]$^{+}$ cations and [ClO$_{4}$]$^{-}$ anions. Introduction of chlorine atoms into the β‐positions of the hexacyclic rings of the tetraazamacrocycle hardly changes the lengths of the delocalized C $$\begin{gathered} --- \enspace\enspace \\ \ldots \enspace\enspace \\\end{gathered}$$ N and C $$\begin{gathered} --- \enspace\enspace \\ \ldots \enspace\enspace \\\end{gathered}$$ C bonds.
Starting Page	68
Ending Page	73
Page Count	6
File Format	PDF
ISSN	00224766
Journal	Journal of Structural Chemistry
Volume Number	44
Issue Number	1
e-ISSN	15738779
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2003-01-01
Publisher Place	New York
Access Restriction	Subscribed
Subject Keyword	Inorganic Chemistry Physical Chemistry Atoms, Molecules, Clusters and Plasmas
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Inorganic Chemistry Physical and Theoretical Chemistry

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Introduction of halogen atoms into gold(III) tetraaza metallocomplexes. Crystal and molecular structure of [Au(C$_{9}$H$_{18}$N$_{4}$Br)](ClO$_{4}$)$_{2}$ and [Au(C$_{14}$H$_{20}$N$_{4}$Br$_{2}$)]ClO$_{4}$

Synthesis and crystal and molecular structure of β-chlorinated acyclic complex of gold(III) [Au(C$_{9}$H$_{18}$N$_{4}$Cl)](ClO$_{4}$)$_{2}$

Investigation of Protonation of the Tetraazamacrocyclic Complex of Gold(III) [Au(C$_{14}$H$_{22}$N$_{4}$)]$^{+}$ in Water. Synthesis and Crystal and Molecular Structures of [Au(C$_{14}$H$_{23}$N$_{4}$)](ClO$_{4}$)$_{2}$

Protonation of the acyclic tetraaza metallocomplex of gold(III) [Au(C$_{9}$H$_{19}$N$_{4}$)]$^{2+}$ in aqueous solution. Synthesis and crystal and molecular structure of [Au(C$_{9}$H$_{20}$N$_{4}$)](H$_{5}$O$_{2}$)(ClO$_{4}$)$_{4}$

Crystal and molecular structure of [Au(C$_{14}$H$_{24}$N$_{4}$)][H$_{3}$O](ClO$_{4}$)$_{4}$

Gold(III) ionic complexes [Au{S$_{2}$CN(C$_{2}$H$_{5}$)$_{2}$}$_{2}$]Cl and ([Au{S$_{2}$CN(C$_{2}$H$_{5}$)$_{2}$}$_{2}$][AuCl$_{4}$])$_{ n }$: Synthesis, supramolecular self-assembly, polymorphism, and thermal behavior

Crystal and Molecular Structure of 5,7,12,14-Tetramethyl-1,4,8,11-tetraaza-4,6,11,13-tetraenatogold(III) Bromide [Au(C$_{14}$H$_{22}$N$_{4}$)]Br

Crystal Structure of a Supramolecular Adduct of Tetrachloroferrate(III) with Cucurbituryl (H$_{7}$O$_{3}$)$_{4}$[FeCl$_{4}$]$_{2}$Cl$_{2}$⋅C$_{36}$H$_{36}$N$_{24}$O$_{12}$⋅3H$_{2}$O

Polynuclear complexes of gold(III) of the composition ([Au(S$_{2}$CNR$_{2}$)$_{2}$][AuCl$_{4}$])$_{ n }$ (R = C$_{4}$H$_{9}$, R$_{2}$ = (CH$_{2}$)$_{5}$): Synthesis, supramolecular structures, and thermal behavior

Synthesis of β‐Chlorinated Macrocyclic [Au(C$_{14}$H$_{20}$N$_{4}$Cl$_{2}$)]X (X = AuCl$_{2}$, ClO$_{4}$, AuCl$_{4}$) Gold(III) Complexes. Crystal and Molecular Structures of [Au(C$_{14}$H$_{20}$N$_{4}$Cl$_{2}$)]ClO$_{4}$

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