NDLI: Crystal structure of a novel complex [Co(3,3′-bpbc)(H$_{2}$O)$_{3}$]·H$

Content Provider	SpringerLink
Author	Gao, E. J. Jiang, L. L. Zhang, D. Jiao, W. Liu, T. L. Zhang, Y. J. Wu, G. L. Xu, J.
Copyright Year	2013
Abstract	A novel coordination polymer constructed with [Co(3,3′-bpbc)(H$_{2}$O)$_{3}$]·H$_{2}$O(I) (3,3′-bpbc = 2,2′-bipyridine-3,3′-dicarboxylic acid) is successfully synthesized at room temperature and characterized by elemental analysis and IR spectra. The crystal structure of the complex is determined by single crystal X-ray diffraction. The unit cell parameters for complex I are: a = 9.9606(11) Å, b = 9.2552(10) Å, c = 16.0258(17) Å, β = 96.731(0)°, V = 1467.2(3) Å$^{3}$, Z = 4, space group P2(1)/n. In the crystal, the cobalt(II) ion adopts a hexa-coordinate environment, and the structure units aggregate together to give birth to infinite 1D chains. The 2D and 3D framework is constructed via intermolecular hydrogen bonds.
Starting Page	978
Ending Page	982
Page Count	5
File Format	PDF
ISSN	00224766
Journal	Journal of Structural Chemistry
Volume Number	54
Issue Number	5
e-ISSN	15738779
Language	English
Publisher	Springer US
Publisher Date	2013-11-29
Publisher Place	Boston
Access Restriction	Subscribed
Subject Keyword	2,2′-bipyridine-3,3′-dicarboxylic acid (3,3′-bpbc) cobalt(II) complex crystal structure coordination Inorganic Chemistry Physical Chemistry Atomic, Molecular, Optical and Plasma Physics Atomic/Molecular Structure and Spectra Solid State Physics
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Inorganic Chemistry Physical and Theoretical Chemistry

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