NDLI: Cu(II) and Zn(II)-Pyridine-2,3-Dicarboxylate Complexes with 2-Methylimidazole: Syntheses, Crystal Structures, Spectroscopic and Thermal Analyses

Content Provider	SpringerLink
Author	Semerci, Fatih Yeşilel, Okan Zafer Şahin, Ertan
Copyright Year	2010
Abstract	Two new Cu(II) and Zn(II)-pyridine-2,3-dicarboxylate (pydc) complexes with 2-methylimidazole (2-Meim), [Cu(pydc)(2-Meim)$_{3}$]·H$_{2}$O (1) and {[Zn(μ-pydc)(H$_{2}$O)(2-Meim)]·H$_{2}$O}$_{n}$ (2) have been synthesized and characterized by elemental, spectral (IR and UV–Vis.) and thermal analyses. The molecular structures of mononuclear (1) and polynuclear (2) complexes have been determined by the single crystal X-ray diffraction. Compound 1 crystallizes in the triclinic P − 1 space group, while compound 2 crystallizes in the monoclinic P2$_{1}$/c space group. The pyridine-2,3-dicarboxylate ligand acts in two different coordination modes; namely, bidentate-(N,O) for 1 and μ-tridentate-(N,O,O) for 2, the latter displaying a 1D polynuclear structure. The crystal packing of the complexes exhibit 3D supramolecular frameworks including channels by C–H···π, π···π, and N–H···O interactions. Water molecules occupy the channels by O–H···O hydrogen bonds.
Starting Page	334
Ending Page	342
Page Count	9
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	20
Issue Number	2
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2010-04-10
Publisher Place	Boston
Access Restriction	Subscribed
Subject Keyword	Pyridine-2,3-dicarboxylic acid Pyridine-2,3-dicarboxylate complexes 2-Methylimidazole complexes Thermal analysis Polymer Sciences Organic Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

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