NDLI: The First Two Examples of (R)-2-Chloromandelato Coordination Polymers: Synthesis, Structure, Magnetic and Ferroelectric Properties

Content Provider	SpringerLink
Author	Qi, JinLi Ni, ShengLiang Xu, Wei Qian, JianYong Zheng, YueQing
Copyright Year	2014
Abstract	Both (R)-2-Chloromandelato coordination polymers, [Cu(Clma)$_{2}$]$_{ n }$ 1 and [Mn(H$_{2}$O)(Clma)$_{2}$]$_{ n }$ 2, crystallizing in the polar chiral monoclinic space group P2$_{1}$ represent the first two examples of metal complexes with (R)-2-Chloromandelic acid (HClma) ligand. Through the (R)-2-Chloromandelate Clma$^{−}$ ions, the penta- and hexa-coordinated metal atoms in 1 and 2 are linked into chains, ∞ 1 {[Cu(Clma)](Clma)$_{2/2}$}$_{ n }$ and ∞ 1 {[Mn(H$_{2}$O)(Clma)](Clma)$_{2/2}$}$_{ n }$, respectively, and further assembled into 3D supramolecular architectures via hydrogen bonding and close packing interactions. They exhibit ferroelectricity (Pr = 0.03 and 0.01 μC cm$^{−2}$, Ec = 5.09 and 0.52 kV cm$^{−1}$, Ps = 0.10 and 0.17 μC cm$^{−2}$, respectively). The magnetic behaviors of 1 and 2 can be interpreted by means of a 1D chain model, where the magnetic exchanges are transmitted via carboxylate groups between metal atoms, and the best fit results in J = 2.97, −0.15 cm$^{−1}$ for 1 and 2, suggesting ferromagnetic and antiferromagnetic interactions, respectively.
Starting Page	600
Ending Page	607
Page Count	8
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	24
Issue Number	3
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2014-02-12
Publisher Place	Boston
Access Restriction	Subscribed
Subject Keyword	(R)-2-Chloromandelic acid Chiral complexes Magnetic properties Ferroelectric properties Inorganic Chemistry Organic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

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