NDLI: Syntheses, Crystal Structure and Luminescent Properties of Co-ordination Networks Based on Copper(I) Iodide Clusters from 1, 4-Bis(imidazole-1-ylmethyl)benzene

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Syntheses, Crystal Structure and Luminescent Properties of Co-ordination Networks Based on Copper(I) Iodide Clusters from 1, 4-Bis(imidazole-1-ylmethyl)benzene

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Syntheses, Crystal Structure and Luminescent Properties of Co-ordination Networks Based on Copper(I) Iodide Clusters from 1, 4-Bis(imidazole-1-ylmethyl)benzene

Content Provider	SpringerLink
Author	Li, Tao Du, Shao Wu
Copyright Year	2007
Abstract	This paper presents novel and distinctive Copper(I) iodide polymers with intriguing structure motifs, constructed from 1, 4-bis(imidazole-1-ylmethyl)benzene (bix). Treatment of bix with CuI generated [(Cu$_{4}$I$_{4}$)(bix)$_{2}$]$_{ n }$ 1, whose X-ray single crystal structural determination revealed a novel 2-D battlement-like sheet structure with square grids based on distorted cubane-like Cu$_{4}$I$_{4}$ clusters. The structural features and photoluminescence of the complexes are discussed. The present finding may provide insight into the coordination versatility of copper(I) halide clusters with N-donor ligands and an inspiration for the self-assembly of novel supramolecular networks based on copper(I) halide clusters.
Starting Page	323
Ending Page	330
Page Count	8
File Format	PDF
ISSN	10407278
Journal	Journal of Cluster Science
Volume Number	19
Issue Number	1
e-ISSN	15728862
Language	English
Publisher	Springer US
Publisher Date	2008-01-03
Publisher Place	Boston
Access Restriction	Subscribed
Subject Keyword	Crystal structure Supramolecular (4,4) Topology Luminescence Inorganic Chemistry Physical Chemistry Catalysis
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics Biochemistry Chemistry Materials Science

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Syntheses, Crystal Structure and Luminescent Properties of Co-ordination Networks Based on Copper(I) Iodide Clusters from 1, 4-Bis(imidazole-1-ylmethyl)benzene

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