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  1. Archives of Environmental Contamination and Toxicology
  2. Archives of Environmental Contamination and Toxicology : Volume 57
  3. Archives of Environmental Contamination and Toxicology : Volume 57, Issue 2, August 2009
  4. Oxidative Transformation of 17β-estradiol by MnO2 in Aqueous Solution
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Archives of Environmental Contamination and Toxicology : Volume 72
Archives of Environmental Contamination and Toxicology : Volume 71
Archives of Environmental Contamination and Toxicology : Volume 70
Archives of Environmental Contamination and Toxicology : Volume 69
Archives of Environmental Contamination and Toxicology : Volume 68
Archives of Environmental Contamination and Toxicology : Volume 67
Archives of Environmental Contamination and Toxicology : Volume 66
Archives of Environmental Contamination and Toxicology : Volume 65
Archives of Environmental Contamination and Toxicology : Volume 64
Archives of Environmental Contamination and Toxicology : Volume 63
Archives of Environmental Contamination and Toxicology : Volume 62
Archives of Environmental Contamination and Toxicology : Volume 61
Archives of Environmental Contamination and Toxicology : Volume 60
Archives of Environmental Contamination and Toxicology : Volume 59
Archives of Environmental Contamination and Toxicology : Volume 58
Archives of Environmental Contamination and Toxicology : Volume 57
Archives of Environmental Contamination and Toxicology : Volume 57, Issue 4, November 2009
Archives of Environmental Contamination and Toxicology : Volume 57, Issue 3, October 2009
Archives of Environmental Contamination and Toxicology : Volume 57, Issue 2, August 2009
Combined Use of Bioindicators and Passive Samplers for the Assessment of River Water Contamination With Metals
Oxidative Transformation of 17β-estradiol by MnO2 in Aqueous Solution
Sequential Extractions and Isotope Analysis for Discriminating the Chemical Forms and Origins of Pb in Sediment from Liaodong Bay, China
Using Acetone as Solvent to Study Removal of Anthracene in Soil Inhibits Microbial Activity and Alters Nitrogen Dynamics
Occurrence and Fate of Organochlorinated Pesticides and PAH in Agricultural Soils from the Ebro River Basin
Necessity of Screening Water Chestnuts for Microcystins After Cyanobacterial Blooms Break Out
Effects of a Realistic Mixture of Antibiotics on Resistant and Nonresistant Sewage Sludge Bacteria in Laboratory-Scale Treatment Plants
Natural DOM Affects Copper Speciation and Bioavailability to Bacteria and Ciliate
Ability of Four Emergent Macrophytes to Remediate Permethrin in Mesocosm Experiments
Carryover of Perfluorooctanoic Acid (PFOA) and Perfluorooctane Sulfonate (PFOS) from Soil to Plants
Characterization of Cadmium Uptake and Translocation in a Cadmium-Sensitive Mutant of Rice (Oryza sativa L. ssp. japonica)
Textile Effluents Induce Biomarkers of Acute Toxicity, Oxidative Stress, and Genotoxicity
Toxicity of Sediment Cores Collected from the Ashtabula River in Northeastern Ohio, USA, to the Amphipod Hyalella azteca
Effects of Environmental Contaminants on Hemoglobin Gene Expression in Daphnia magna: A Potential Biomarker for Freshwater Quality Monitoring
Toxicokinetics of Waterborne Trivalent Arsenic in the Freshwater Bivalve Corbicula fluminea
Organic Contaminants in the Marine Environment of Manila Bay, Philippines
Accumulation of Lead, Chromium, and Cadmium in Muscle of capitán (Eremophilus mutisii), a Catfish from the Bogota River Basin
Physiological Stress in Native Southern Brook Trout During Episodic Stream Acidification in the Great Smoky Mountains National Park
Biochemical Responses and Accumulation Properties of Long-Chain Perfluorinated Compounds (PFOS/PFDA/PFOA) in Juvenile Chickens (Gallus gallus)
Environmental Contaminants in White-Winged Doves (Zenaida asiatica asiatica) from the Lower Rio Grande Valley of Texas, USA
Levels and Profiles of Polychlorinated Dibenzo-p-Dioxins, Polychlorinated Dibenzofurans, and Polychlorinated Biphenyls in Feedstuffs and Milk From Farms in the Vicinity of Incineration Plants in Tuscany, Italy
Seawater and Shellfish (Geukensia demissa) Quality Along the Western Coast of Assateague Island National Seashore, Maryland: An Area Impacted by Feral Horses and Agricultural Runoff
Hepatic P450 Enzyme Activity, Tissue Morphology and Histology of Mink (Mustela vison) Exposed to Polychlorinated Dibenzofurans
Archives of Environmental Contamination and Toxicology : Volume 57, Issue 1, July 2009
Archives of Environmental Contamination and Toxicology : Volume 56
Archives of Environmental Contamination and Toxicology : Volume 55
Archives of Environmental Contamination and Toxicology : Volume 54
Archives of Environmental Contamination and Toxicology : Volume 53
Archives of Environmental Contamination and Toxicology : Volume 52
Archives of Environmental Contamination and Toxicology : Volume 51
Archives of Environmental Contamination and Toxicology : Volume 50
Archives of Environmental Contamination and Toxicology : Volume 49
Archives of Environmental Contamination and Toxicology : Volume 48
Archives of Environmental Contamination and Toxicology : Volume 47
Archives of Environmental Contamination and Toxicology : Volume 46
Archives of Environmental Contamination and Toxicology : Volume 45
Archives of Environmental Contamination and Toxicology : Volume 44
Archives of Environmental Contamination and Toxicology : Volume 43
Archives of Environmental Contamination and Toxicology : Volume 42
Archives of Environmental Contamination and Toxicology : Volume 41
Archives of Environmental Contamination and Toxicology : Volume 40
Archives of Environmental Contamination and Toxicology : Volume 39
Archives of Environmental Contamination and Toxicology : Volume 38
Archives of Environmental Contamination and Toxicology : Volume 37
Archives of Environmental Contamination and Toxicology : Volume 36
Archives of Environmental Contamination and Toxicology : Volume 35
Archives of Environmental Contamination and Toxicology : Volume 34
Archives of Environmental Contamination and Toxicology : Volume 33
Archives of Environmental Contamination and Toxicology : Volume 32

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Oxidative Transformation of 17β-estradiol by MnO2 in Aqueous Solution

Content Provider SpringerLink
Author Jiang, Liying Huang, Cheng Chen, Jianmeng Chen, Xiao
Copyright Year 2008
Abstract 17β-Estradiol (E2) is known as a natural endocrine disruptor and often found in municipal sewage. Batch experiments were conducted to assess the oxidative transformation of E2 in aqueous solutions by MnO2 and the probable degradation pathway. The results suggested that E2 could be degraded by MnO2, and the oxidation reaction deviated from pseudo-first-order kinetics due to the accumulation of reaction products in mineral surfaces and a gradual change of the surface site distribution toward less reactive sites. MnO2 dosage had a positive effect on oxidative transformation of E2, and both the initial reaction rate and the adsorption of E2 to oxide surfaces increased as the pH decreased. Two products, estrone and 2-hydroxyestradiol, were detected by gas chromatography coupled with mass spectrometry, and the probable degradation pathway was proposed. Results suggest that E2 can be oxidatively transformed by MnO2, which will provide some new insights into the interaction of estrogens with manganese oxides in natural soils and sediments.
Starting Page 221
Ending Page 229
Page Count 9
File Format PDF
ISSN 00904341
Journal Archives of Environmental Contamination and Toxicology
Volume Number 57
Issue Number 2
e-ISSN 14320703
Language English
Publisher Springer-Verlag
Publisher Date 2008-11-12
Publisher Place New York
Access Restriction One Nation One Subscription (ONOS)
Subject Keyword Environmental Monitoring/Analysis Soil Science & Conservation Environmental Chemistry Environmental Health Pollution Ecotoxicology
Content Type Text
Resource Type Article
Subject Pollution Health, Toxicology and Mutagenesis Medicine Toxicology
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