NDLI: Anomalous Optical Properties of xSrO–10PbO–(90 − x)B$_{2}$O$

Content Provider	SpringerLink
Author	Sabri, Nurul Syahidah Yahya, A. K. Talari, Mahesh Kumar
Copyright Year	2017
Abstract	Raman and UV–Vis spectral analysis of xSrO–10PbO–(90 − x)B$_{2}$O$_{3}$ glasses were carried out to elucidate the structural and optical behaviour due to borate anomaly. Raman analysis revealed that the glasses consisted of mainly trigonal groups (metaborate) and tetrahedral groups (ditri/dipentaborate and diborate) at lower SrO content. Concentration of diborate groups reached a maximum value at x = 30 mol% and were replaced by pyroborate, metaborate and orthoborate groups as SrO content in the glass increased. Maximum value of optical band gap (E $_{ opt }$) and minimum values of electronic polarizability (α$_{O2−}$), optical basicity (Λ) and refractive index (n) were obtained when x = 25 mol%, which was lower compared to maximum of diborate group (x = 30 mol%) as observed from Raman spectroscopic analysis. Observed mismatch in diborate groups and E $_{ opt }$ maxima was attributed to the formation of weak coordinated covalent bonds during structural transformation and addition of cation with high polarizability to the xSrO–10PbO–(90 − x)B$_{2}$O$_{3}$ glass.
Starting Page	557
Ending Page	565
Page Count	9
File Format	PDF
ISSN	09722815
Journal	Transactions of the Indian Institute of Metals
Volume Number	70
Issue Number	3
e-ISSN	09751645
Language	English
Publisher	Springer India
Publisher Date	2017-01-28
Publisher Place	New Delhi
Access Restriction	Subscribed
Subject Keyword	Borate anomaly Raman analysis UV–Vis spectral analysis Glass optical properties Metallic Materials Materials Science Tribology, Corrosion and Coatings
Content Type	Text
Resource Type	Article
Subject	Metals and Alloys

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Libarray of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Structural, Optical, and Ferroelectric Behaviors of Cu$_{1−x }$Li$_{ x }$O (0 ≤ x ≤ 0.09) Nanostructures

Synthesis and Characterization of Lithium Borate Glasses Containing La$_{2}$O$_{3}$

Oxidation and corrosion resistance of TiAl$_{3}$ coatings

Glass formation and nanocrystallization in Zr based alloys

Phase Evolution in Hypereutectic Al$_{90}$Cu$_{10−x}$Ni$_{x}$ (x = 0, 5) Alloys

Limitations and Advantages of Raman Spectroscopy for the Determination of Oxidation Stresses

Glass-Forming Ability of Mg–Cu–Ni–Gd Bulk Metallic Glasses with High Strength

Wear of Plasma Sprayed Conventional and Nanostructured Al$_{2}$O$_{3}$ and Cr$_{2}$O$_{3}$, Based Coatings

The Effect of Al$_{2}$O$_{3}$–TiB$_{2}$/Fe Complex Reinforcement on Wear and Mechanical Properties of Al-Matrix Composites

Anomalous Optical Properties of xSrO–10PbO–(90 − x)B$_{2}$O$_{3}$ Glass System

Similar Documents

Structural, Optical, and Ferroelectric Behaviors of Cu$_{1−x }$Li$_{ x }$O (0 ≤ x ≤ 0.09) Nanostructures

Synthesis and Characterization of Lithium Borate Glasses Containing La$_{2}$O$_{3}$

Oxidation and corrosion resistance of TiAl$_{3}$ coatings

Glass formation and nanocrystallization in Zr based alloys

Phase Evolution in Hypereutectic Al$_{90}$Cu$_{10−x}$Ni$_{x}$ (x = 0, 5) Alloys

Limitations and Advantages of Raman Spectroscopy for the Determination of Oxidation Stresses

Glass-Forming Ability of Mg–Cu–Ni–Gd Bulk Metallic Glasses with High Strength

Wear of Plasma Sprayed Conventional and Nanostructured Al$_{2}$O$_{3}$ and Cr$_{2}$O$_{3}$, Based Coatings

The Effect of Al$_{2}$O$_{3}$–TiB$_{2}$/Fe Complex Reinforcement on Wear and Mechanical Properties of Al-Matrix Composites

Anomalous Optical Properties of xSrO–10PbO–(90 − x)B$_{2}$O$_{3}$ Glass System