NDLI: Synthesis and crystal structures of two isostructural manganese(III) and iron(III) complexes derived from N,N′-bis(3-ethoxysalicylidene)-1,2-propanediamine with cytochrome P450-like hydroxylation properties

Content Provider	SpringerLink
Author	Ma, Xiao Li You, Zhong Lu
Copyright Year	2008
Abstract	Two isostructural mononuclear complexes with the formula [M$^{III}$L(N$_{3}$)(OH$_{2}$)] × 1/2N$_{2}$ (M = Mn for (1) and Fe for (2); H$_{2}$L = N,N′-bis(3-ethoxysalicylidene)-1,2-propanediamine) have been synthesized and characterized by physico-chemical and spectroscopic methods. Each compound consists of a mononuclear complex molecule and half of a nitrogen molecule of crystallization. Each metal atom in the complexes has a slightly distorted octahedral geometry, coordinated by two nitrogen and two phenolic donors of L, the oxygen atom of the water molecule, and the nitrogen atom of the azide group. Determination by GC/MS analysis indicated that complex (1) has no catalytic property for the dioxygen oxidization of cyclohexene, but complex (2) has good properties.
Starting Page	961
Ending Page	965
Page Count	5
File Format	PDF
ISSN	03404285
Journal	Transition Metal Chemistry
Volume Number	33
Issue Number	8
e-ISSN	1572901X
Language	English
Publisher	Springer Netherlands
Publisher Date	2008-08-19
Publisher Place	Dordrecht
Access Restriction	Subscribed
Subject Keyword	Inorganic Chemistry Physical Chemistry Catalysis
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry Materials Chemistry Metals and Alloys

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Synthesis and crystal structures of two isostructural manganese(III) and iron(III) complexes derived from N,N′-bis(3-ethoxysalicylidene)-1,2-propanediamine with cytochrome P450-like hydroxylation properties