NDLI: Investigation of catalytic activity of ZnAl$_{2}$O$_{4}$ and ZnMn$_{2}$O$_{4}$ nanoparticles in the thermal decomposition of ammonium perchlorate : Structural and kinetic studies

Content Provider	SpringerLink
Author	Juibari, Nafise Modanlou Eslami, Abbas
Copyright Year	2016
Abstract	ZnAl$_{2}$O$_{4}$ and ZnMn$_{2}$O$_{4}$ nanoparticles were synthesized by a modified co-precipitation method and characterized by means of Fourier transform infrared spectroscopy, X-ray diffraction, energy-dispersion X-ray spectrometer, and their morphology investigated by means of scanning electron microscopy. The effects of these nanoparticles on the thermal decomposition of ammonium perchlorate (AP) were examined by differential scanning calorimetery and thermogravimetery analyses. The results revealed that ZnAl$_{2}$O$_{4}$ nanoparticles have little catalytic effect on this process, but ZnMn$_{2}$O$_{4}$ nanoparticles have good catalytic effect on decreasing the decomposition temperature of AP and increasing the released heat. ZnAl$_{2}$O$_{4}$ and ZnMn$_{2}$O$_{4}$ nanoparticles increased the released heat of AP decomposition from 400 to about 736 and 1130 Jg$^{−1}$, respectively, and AP decomposition temperature decreased from 420 to 400 and 358 °C in the same order. The higher catalytic activity of ZnMn$_{2}$O$_{4}$ can be due to its p-type semiconductivity and the presence of some positive hole and defects. Also, the kinetic parameters such as pre-exponential factor and activation energy were calculated using Kissinger method.
Starting Page	115
Ending Page	124
Page Count	10
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	128
Issue Number	1
e-ISSN	15882926
Language	English
Publisher	Springer Netherlands
Publisher Date	2016-10-31
Publisher Place	Dordrecht
Access Restriction	Subscribed
Subject Keyword	Co-precipitation ZnAl$_{2}$O$_{4}$ and ZnMn$_{2}$O$_{4}$ nanoparticles Ammonium perchlorate Spinel Thermal decomposition Catalytic effect Physical Chemistry Analytical Chemistry Polymer Sciences Inorganic Chemistry Measurement Science and Instrumentation
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics Physical and Theoretical Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Libarray of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

The effect of average particle size of nano-Co$_{3}$O$_{4}$ on the catalytic thermal decomposition of ammonium perchlorate particles

CuO nanocrystals in thermal decomposition of ammonium perchlorate : Stabilization, structural characterization and catalytic activities

Cu–Cr–Pb nanocomposites : Synthesis, characterization and their catalytic effect on thermal decomposition of ammonium perchlorate

Synthesis of α-Fe$_{2}$O$_{3}$ nanoparticles by dry high-energy ball-milling method and investigation of their catalytic activity

Preparation of NdCrO$_{3}$ nanoparticles and their catalytic activity in the thermal decomposition of ammonium perchlorate by DSC/TG-MS

Synthesis of CuO nanopowders by high-energy ball-milling method and investigation of their catalytic activity on thermal decomposition of ammonium perchlorate particles

Thermal decomposition of ammonium perchlorate based mixture with fullerenes

Improvement of thermal decomposition properties of ammonium perchlorate particles using some polymer coating agents

Thermal decomposition of ammonium perchlorate activated via addition of NiO nanocrystals

Investigation of catalytic activity of ZnAl$_{2}$O$_{4}$ and ZnMn$_{2}$O$_{4}$ nanoparticles in the thermal decomposition of ammonium perchlorate : Structural and kinetic studies

Similar Documents

The effect of average particle size of nano-Co$_{3}$O$_{4}$ on the catalytic thermal decomposition of ammonium perchlorate particles

CuO nanocrystals in thermal decomposition of ammonium perchlorate : Stabilization, structural characterization and catalytic activities

Cu–Cr–Pb nanocomposites : Synthesis, characterization and their catalytic effect on thermal decomposition of ammonium perchlorate

Synthesis of α-Fe$_{2}$O$_{3}$ nanoparticles by dry high-energy ball-milling method and investigation of their catalytic activity

Preparation of NdCrO$_{3}$ nanoparticles and their catalytic activity in the thermal decomposition of ammonium perchlorate by DSC/TG-MS

Synthesis of CuO nanopowders by high-energy ball-milling method and investigation of their catalytic activity on thermal decomposition of ammonium perchlorate particles

Thermal decomposition of ammonium perchlorate based mixture with fullerenes

Improvement of thermal decomposition properties of ammonium perchlorate particles using some polymer coating agents

Thermal decomposition of ammonium perchlorate activated via addition of NiO nanocrystals

Investigation of catalytic activity of ZnAl$_{2}$O$_{4}$ and ZnMn$_{2}$O$_{4}$ nanoparticles in the thermal decomposition of ammonium perchlorate : Structural and kinetic studies