NDLI: Synthesis and Crystal Structure of Nitrotriammine Complex of Nitrosoruthenium(II) [RuNO(NH$_{3}$)$_{3}$(NO$_{2}$)(OH)]Cl·0.5H$

Content Provider	SpringerLink
Author	Emel’yav, V. A. Gromilov, S. A. Baidina, I. A.
Copyright Year	2004
Abstract	Procedures for the synthesis of the [RuNO(NH$_{3}$ $_{3}$(NO$_{2}$)(OH)]Cl·0.5H$_{2}$O complex have been developed. The compound was investigated by IR spectroscopy, and also by powder and single crystal X-ray diffraction. Crystal data for H$_{11}$CIN$_{5}$O$_{4.5}$Ru: a = 6.5752(7) Å, b = 11.0900(18) Å, c = 12.296(2) Å, ά = 79.692(13)°, β = 85.088(11)°, γ = 87.395(11)°, V = 878.5(2) Å$^{3}$, Z = 4, d $_{calc}$ = 2.190 g/cm$^{3}$, space group $$P\bar 1$$ . The structure is formed by [RuNO(NH$_{3}$)$_{3}$(NO$_{2}$)(OH)]$^{+}$] complex cations, Cl$^{−}$ anions, and crystallization water molecules. The complex crystallizes as yellow transparent prisms belonging to the triclinic crystal system; it is soluble in water and insoluble in ethanol and acetone. The crystals are stable when kept in a closed beaker, but gradually degrade in dry air.
Starting Page	879
Ending Page	888
Page Count	10
File Format	PDF
ISSN	00224766
Journal	Journal of Structural Chemistry
Volume Number	45
Issue Number	5
e-ISSN	15738779
Language	English
Publisher	Kluwer Academic Publishers-Consultants Bureau
Publisher Date	2004-01-01
Publisher Place	New York
Access Restriction	Subscribed
Subject Keyword	ruthenium nitroso complexes amino complexes X-ray structural analysis crystal chemistry Inorganic Chemistry Physical Chemistry Atoms, Molecules, Clusters and Plasmas Atomic and Molecular Structure and Spectra Solid State Physics and Spectroscopy
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Inorganic Chemistry Physical and Theoretical Chemistry

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