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Content Provider | SpringerLink |
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Author | Jiang, X. S. Pan, H. L. Feng, Z. B. Wu, H. T. |
Copyright Year | 2016 |
Abstract | Wolframite structure NiZrNb$_{2}$O$_{8}$ ceramics were prepared by the solid state reaction method. Sintering characteristics and microwave dielectric properties were investigated under various sintering temperatures ranging from 1100 to 1300 °C. The micro-structure, crystal structure and phase composition were studied by the scanning electron microscopy techniques, X-ray diffraction and energy disperse spectroscopy, respectively. Refinement was used to analyze the crystal structure. Based on the cell parameters, the chemical bond theory was used to calculate the lattice energy, bond ionicity and the coefficient of thermal expansion for the characterization of correlations between properties and structures of NiZrNb$_{2}$O$_{8}$ ceramics. The microwave dielectric properties of NiZrNb$_{2}$O$_{8}$ were strongly dependent on the chemical bond ionicity, lattice energy and coefficient of thermal expansion. The ε $_{ r }$ values could be strongly dependent on the bond ionicity of the Nb–O bonds. The Q·f values were affected by the lattice energy of Nb–O bonds. As for the τ $_{ f }$ values, it could be mainly affected by the coefficient of thermal expansion of Ni–O bonds. At the sintering temperature of 1250 °C, NiZrNb$_{2}$O$_{8}$ ceramics exhibited the excellent microwave properties of ε $_{ r }$ = 18.84, Q·f = 18, 142 GHz and τ $_{ f }$ = −35.43 ppm/°C. |
Starting Page | 10963 |
Ending Page | 10969 |
Page Count | 7 |
File Format | |
ISSN | 09574522 |
Journal | Journal of Materials Science: Materials in Electronics |
Volume Number | 27 |
Issue Number | 10 |
e-ISSN | 1573482X |
Language | English |
Publisher | Springer US |
Publisher Date | 2016-06-24 |
Publisher Place | New York |
Access Restriction | Subscribed |
Subject Keyword | Optical and Electronic Materials Characterization and Evaluation of Materials |
Content Type | Text |
Resource Type | Article |
Subject | Biomedical Engineering Electronic, Optical and Magnetic Materials Bioengineering Condensed Matter Physics Biophysics Atomic and Molecular Physics, and Optics Electrical and Electronic Engineering Biomaterials |
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