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Author Alper, H. ♦ Paik, H. N.
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Language English
Subject Keyword INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ♦ COAL, LIGNITE, AND PEAT ♦ DESULFURIZATION ♦ REAGENTS ♦ ORGANIC SULFUR COMPOUNDS ♦ CARBONYLS ♦ CHEMICAL REACTION KINETICS ♦ COBALT COMPOUNDS ♦ FUEL OILS ♦ IRON COMPOUNDS ♦ POTASSIUM HYDROXIDES ♦ ALKALI METAL COMPOUNDS ♦ CHEMICAL REACTIONS ♦ FUELS ♦ HYDROGEN COMPOUNDS ♦ HYDROXIDES ♦ KINETICS ♦ OILS ♦ ORGANIC COMPOUNDS ♦ OTHER ORGANIC COMPOUNDS ♦ OXYGEN COMPOUNDS ♦ PETROLEUM PRODUCTS ♦ POTASSIUM COMPOUNDS ♦ REACTION KINETICS ♦ TRANSITION ELEMENT COMPOUNDS ♦ Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ♦ Coal, Lignite, & Peat- Purification & Upgrading
Abstract Hydrocarbons and amines are formed in good yields by treatment of thioketones and thioamides, respectively, with iron pentacarbonyl and potassium hydroxide (i.e., HFe(CO)/sub 4//sup -/). A different, and useful, desulfurization reaction occurred by the use of dicobalt octacarbonyl, the cobalt tetracarbonyl anion, or cyclopentadienyliron dicarbonyl dimer as reagents. Mechanisms are proposed for several of these reactions.
Educational Use Research
Learning Resource Type Article
Publisher Date 1977-10-28
Publisher Place United States
Journal J. Org. Chem.
Volume Number 42
Issue Number 22
Organization Univ. of Ottawa


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