Thumbnail
Access Restriction
Open

Author Liu, Tong-Huan ♦ Huang, Liang ♦ Chen, Feng-Juan ♦ Xi, Pin-Xian ♦ Xu, Zhi-Hong ♦ Xu, Min ♦ Zeng, Zheng-Zhi
Source J-STAGE
Content type Text
Publisher The Japan Society for Analytical Chemistry
Language English
Abstract A novel binuclear copper(II) complex with 2-(methoxycarbonyl)benzoic acid (HL), N,N-dimethylformamide (DMF) and methanol $[Cu_{2}L_{4}(DMF)(CH_{3}OH)·CH_{3}OH]$ was synthesized. The complex was crystallized in the monoclinic system. The space group was Pn with a = 14.410(3)Å, b = 10.540(2)Å, c = 14.496(3)Å, β = 91.082(4)°, V = $2201.4(9)Å^{3}$ and Z = 2. The final R value was 0.0227. Each Cu(II) ion is coordinated by four carboxylate O donor atoms from four ligands, and by O donor atoms from the solvent molecule, DMF for Cu(1); for Cu(2) it is the O atom of methanol. The whole molecule looks like a “pedal-wheel”. The O-H…O hydrogen bonds between the compound and the solvent molecule stabilize the crystal structure by causing the formation of a one-dimensional chain structure.
Learning Resource Type Article
Publisher Date 2008-01-01
e-ISSN 13482238
Journal Analytical Sciences: X-ray Structure Analysis Online(analscix)
Volume Number 24


Open content in new tab

   Open content in new tab