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Author Schiffer, J.
Sponsorship USDOE
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Publisher American Institute of Physics (AIP)
Language English
Subject Keyword Chemistry-Inorganic, Organic, & Physical Chemistry-Isotopic Effects ♦ Chemistry-Inorganic & Physical Chemistry-Isotope Effects ♦ DEUTERIUM- ISOTOPE EFFECTS ♦ HYDRATION ♦ INFRARED SPECTRA ♦ VIBRATIONAL STATES ♦ WATER
Abstract The separation between uncoupled $nu$sub 3$ and $nu$sub 1$ frequencies of water symmetrically bound in both nonaqueous solvents and hydrates has been shown to vary linearly with the HOD stretching frequency of water, for both H$sub 2$O and D$sub 2$O. This relation, the FS correlation, has been explored theoretically and it has been shown to be useful for estimating geometry changes of water in hydrates, upon deuteration. It is also useful in determining the effect of cation coordination on the stretching frequencies of water molecules. A method is also developed, using this relation, for systematically analyzing the origin of the stretching bands of water in condensed systems. (AIP)
ISSN 00219606
Educational Use Research
Learning Resource Type Article
Publisher Date 1976-04-01
Publisher Department Department of Chemistry, Temple University of the Commonwealth System of Higher Education, Philadelphia, Pennsylvania 19122
Publisher Place United States
Journal Journal of Chemical Physics
Volume Number 64
Issue Number 7
Organization Department of Chemistry, Temple University of the Commonwealth System of Higher Education, Philadelphia, Pennsylvania 19122


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