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Author Lott, D. R. ♦ Fincher, T. ♦ LeBret, G. C. ♦ Cleary, D. A. ♦ Breneman, G. L.
Sponsorship National Science Foundation, Washington, DC (United States)
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Language English
Subject Keyword MATERIALS SCIENCE ♦ CRYSTAL STRUCTURE ♦ SYNTHESIS ♦ ZIRCONIUM SULFIDES ♦ PHOSPHORUS SULFIDES ♦ X-RAY DIFFRACTION ♦ LATTICE PARAMETERS ♦ BOND LENGTHS ♦ BOND ANGLE ♦ EXPERIMENTAL DATA
Abstract Two new compounds have been synthesized and characterized: ZrP{sub 2}S{sub 6} and ZrP{sub 2}S{sub 7}. Both were prepared from direct combination of the elements at high temperature using a chemical transporting agent. Single crystal X-ray diffraction and elemental analysis (ICP-AE) were performed on the materials. ZrP{sub 2}S{sub 6} crystallized in a tetragonal space group (P-4, a = 6.6758(4) {angstrom}, c = 9.491(1) {angstrom}) whereas the ZrP{sub 2}S{sub 7} crystallized in a monoclinic space group (C2/c, a = 8.614(1) {angstrom}, b = 29.684(4) {angstrom}, c = 8.583(1) {angstrom}, {beta} = 120.126{degree}). The ZrP{sub 2}S{sub 6} displayed a weak second harmonic generation at 1064 nm.
ISSN 00224596
Educational Use Research
Learning Resource Type Article
Publisher Date 1999-03-01
Publisher Place United States
Journal Journal of Solid State Chemistry
Volume Number 143
Issue Number 2


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