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Author Sawyer, D. T. ♦ McKinnie, J. M.
Sponsorship USDOE
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Language English
Subject Keyword CHEMISTRY ♦ ABSORPTION ♦ ALUMINUM COMPLEXES ♦ BISMUTH COMPLEXES ♦ CERIUM COMPLEXES ♦ CHELATES ♦ CHEMICAL REACTIONS ♦ CHROMIUM COMPLEXES ♦ COBALT COMPLEXES ♦ COMPLEXES ♦ CONFIGURATION ♦ EDTA ♦ INFRARED RADIATION ♦ IRON COMPLEXES ♦ MOLYBDENUM COMPLEXES ♦ SPECTRA ♦ THORIUM COMPLEXES ♦ TITANIUM COMPLEXES ♦ VANADIUM COMPLEXES
Abstract Infrared spectra were recorded for the EDTA chelates of Al(III), Ce(III), Bi(III), V(III), V (IV), Cr(III), Fe(III), Co(III), Ti(IV), Th(IV), Mo(V), and I(Mo(VI). The spectra, when related to previous studies, indicate that the bonding between ligand and metal ion is primarily ionic for the Al(III), Ce(III), and Bi(III) chelates, and primarily covalent for the remainder of the chelates. Correlations are made between the various functional groups and their resulting absorption peaks. The EDTA chelates for this group of metal ions were synthesized and isolated. (auth)
ISSN 00027863
Educational Use Research
Learning Resource Type Article
Publisher Date 1960-08-20
Publisher Department Univ. of California, Riverside
Journal Journal of the American Chemical Society
Volume Number 82
Organization Univ. of California, Riverside


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