|Author||Sawyer, D. T. ♦ McKinnie, J. M.|
|Source||United States Department of Energy Office of Scientific and Technical Information|
|Subject Keyword||CHEMISTRY ♦ ABSORPTION ♦ ALUMINUM COMPLEXES ♦ BISMUTH COMPLEXES ♦ CERIUM COMPLEXES ♦ CHELATES ♦ CHEMICAL REACTIONS ♦ CHROMIUM COMPLEXES ♦ COBALT COMPLEXES ♦ COMPLEXES ♦ CONFIGURATION ♦ EDTA ♦ INFRARED RADIATION ♦ IRON COMPLEXES ♦ MOLYBDENUM COMPLEXES ♦ SPECTRA ♦ THORIUM COMPLEXES ♦ TITANIUM COMPLEXES ♦ VANADIUM COMPLEXES|
|Abstract||Infrared spectra were recorded for the EDTA chelates of Al(III), Ce(III), Bi(III), V(III), V (IV), Cr(III), Fe(III), Co(III), Ti(IV), Th(IV), Mo(V), and I(Mo(VI). The spectra, when related to previous studies, indicate that the bonding between ligand and metal ion is primarily ionic for the Al(III), Ce(III), and Bi(III) chelates, and primarily covalent for the remainder of the chelates. Correlations are made between the various functional groups and their resulting absorption peaks. The EDTA chelates for this group of metal ions were synthesized and isolated. (auth)|
|Learning Resource Type||Article|
|Publisher Department||Univ. of California, Riverside|
|Journal||Journal of the American Chemical Society|
|Organization||Univ. of California, Riverside|
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