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Author Vuorema, A. ♦ John, P. ♦ Keskitalo, M. ♦ Mahon, M. F. ♦ Anbukulandainathan, M. ♦ Marken, F.
Source CSIR-Central Electrochemical Research Institute
Content type Text
Publisher Royal Society of Chemistry
File Format PDF
Copyright Year ©2009
Language English
Subject Domain (in DDC) Natural sciences & mathematics ♦ Chemistry & allied sciences
Subject Keyword Electroorganic
Abstract Anthraquinone immobilised onto the surface of indigo microcrystals enhances the reductive dissolution of indigo to leuco-indigo. Indigo reduction is driven by glucose in aqueous NaOH and a vibrating gold disc electrode is employed to monitor the increasing leuco-indigo concentration with time. Anthraquinone introduces a strong catalytic effect which is explained by invoking a molecular ‘‘wedge effect’’ during co-intercalation of Na+ and anthraquinone into the layered indigo crystal structure. The glucose-driven indigo reduction, which is ineffective in 0.1 M NaOH at 65 1C, becomes facile and goes to completion in the presence of anthraquinone catalyst. Electron microscopy of indigo crystals before and after reductive dissolution confirms a delamination mechanism initiated at the edges of the plate-like indigo crystals. Catalysis occurs when the anthraquinone–indigo mixture reaches a molar ratio of 1 : 400 (at 65 1C; corresponding to 3 mM anthraquinone) with excess of anthraquinone having virtually no effect. A strong temperature effect (with a composite EA E 120 kJ mol�1) is observed for the reductive dissolution in the presence of anthraquinone. The molar ratio and temperature effects are both consistent with the heterogeneous nature of the anthraquinone catalysis in the aqueous reaction mixture.
Educational Use Research
Education Level UG and PG
Learning Resource Type Article
Publisher Date 2009-01-01
Journal PeerReviewed