Access Restriction

Author Krisnamoorthy, S. ♦ Ravichandran, S. ♦ Noel, M. ♦ Jayaraman, K. ♦ Subbhiah, P. ♦ Chidambaram, S.
Source CSIR-Central Electrochemical Research Institute
Content type Text
Publisher Central Electrochemical Research Institute
File Format PDF
Copyright Year ©1998
Language English
Subject Domain (in DDC) Natural sciences & mathematics ♦ Chemistry & allied sciences
Subject Keyword Electroorganic
Abstract The effect of different operating parameters on the electrochemical perDuorination (ECPF) of oelanoyl chloride was studied in detail. TIle effect of pre-electrolysis time, cell volwge, concentration of the reaewnt and the time disb"ibution of reacwnt in the electrolyte and the overall charge passed on the yield and product distribution are presented. The advantages of operating the cell at constant current density within a specified cell voltage range are also highlighted. The optimum operating conditions arrived at for octanoyl chloride was also found to be suitable for the ECPF of hexanoyl and decanoyl chlorides.
Educational Use Research
Education Level UG and PG
Learning Resource Type Article
Publisher Date 1998-01-01
Journal PeerReviewed