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Author Suryanarayanan, V. ♦ Chellammal, S. ♦ Noel, M.
Source CSIR-Central Electrochemical Research Institute
Content type Text
Publisher Elsevier BV
File Format PDF
Copyright Year ©1999
Language English
Subject Domain (in DDC) Natural sciences & mathematics ♦ Chemistry & allied sciences
Subject Keyword Electroorganic
Abstract Cyclic voltammetric behaviour of a-(phenylthio)acetamides and a-(phenylthio)acetates were compared in CH3CN tetrabutylammonium perchlorate (TBAP) and CH3CN Et3N 3HF to assess the in�uence of �uoride ion on the oxidative pathway. These studies support the Pummerer mechanistic pathway involving an initial attack at sulfur in selective electro�uorination (SEF). A linear correlation between the peak current values in cyclic voltammetry and overall synthetic yield in preparative electrolysis was obtained suggesting the importance of weak blocking or a reactive adsorption effect on the overall synthetic processes. Other factors in�uencing the adsorption and insulation of electrode surfaces during the SEF are also discussed.
Educational Use Research
Education Level UG and PG
Learning Resource Type Article
Publisher Date 1999-01-01
Journal PeerReviewed