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Author Pimblott, S. M. ♦ LaVerne, J. A. ♦ Bartels, D. M. ♦ Jonah, C. D.
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Language English
Subject Keyword PHYSICS ♦ CHEMISTRY ♦ MATHEMATICS, COMPUTERS, INFORMATION SCIENCE, MANAGEMENT, LAW, MISCELLANEOUS ♦ SOLVATED ELECTRONS ♦ HYDRATION ♦ KINETICS ♦ SPATIAL DISTRIBUTION ♦ WATER ♦ RADIOLYSIS ♦ METHYL CHLORIDE ♦ CHEMICAL REACTION KINETICS
Abstract The long-standing discrepancy between the kinetics of the hydrated electron measured in pulse radiolysis experiments and the time dependent decay inferred from the inverse Laplace transform of scavenger data is resolved by the incorporation of an improved measurement of the rate coefficient for the CH{sub 3}Cl + e{sub aq}{sup -} reaction used in the inverse Laplace transform treatment. The revised analysis of both data types leads to the conclusion that the spatial distribution of secondary electrons produced in the energetic electron radiolysis of water is nearly twice as wide as suggested by previous studies. 38 refs., 2 figs.
ISSN 00223654
Educational Use Research
Learning Resource Type Article
Publisher Date 1996-05-30
Publisher Department Argonne National Laboratory (ANL), Argonne, IL
Publisher Place United States
Journal Journal of Physical Chemistry
Volume Number 100
Issue Number 22
Organization Argonne National Laboratory (ANL), Argonne, IL


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