|Author||Parry, R. W. ♦ Edwards, L. J.|
|Source||United States Department of Energy Office of Scientific and Technical Information|
|Publisher||American Chemical Society (ACS)|
|Subject Keyword||CHEMISTRY ♦ BORON HYDRIDES ♦ CHEMICAL REACTIONS ♦ CONFIGURATION ♦ REACTION KINETICS|
|Abstract||Stock originally recognized two groups of boron hydrides, the B/sub n/H/ sub a = 4 and B/sub n/H/sub n + series. This classification has been extended and used as a basis for the systematic arrangement of the boron hydrides. Four types of chemical reactions of the boron hydrides are recognized. These are: (1) symmetrical cleavage of the double bridge bond, (2) non-symmetrical cleavage of the double bridge bond, (3) loss of a proton from a hydrogen bridge bond, and (4) loss of molecular hydrogen from the molecule. The type of reaction expected from a given molecule is related to the position of the molecule in the systematic arrangement and to the geometry of the original boron hydride.|
|Learning Resource Type||Article|
|Publisher Department||Callery Chemical Co., Penna. ♦ Univ. of Michigan, Ann Arbor|
|Journal||Journal of the American Chemical Society|
|Organization||Callery Chemical Co., Penna. ♦ Univ. of Michigan, Ann Arbor|
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