|Author||Blander, M. ♦ Blankenship, F. F. ♦ Newton, R. F.|
|Source||United States Department of Energy Office of Scientific and Technical Information|
|Subject Keyword||CHEMISTRY ♦ ELECTRICITY ♦ FUSED SALTS ♦ POTASSIUM CHLORIDES ♦ POTASSIUM NITRATES ♦ SILVER NITRATES ♦ SOLUTIONS ♦ THERMODYNAMICS|
|Abstract||Measurements of the activities of AgNO/sub 3/ were made in a fused salt concentration cell at 370 and 436 deg in dilute solutions of Ag/sup +/ and Cl/ sup -/ ions. The activities of AgNO/sub 3/ obeyed the Nernst law at the low concentrations of AgNO/sub 3/ measured when no Cl/sup -/ ions were present. The dissolution of KCl in a AgNO/sub 3/--KNO/sub 3/ mixture lowered the activity of AgNO/sub 3/. The lowering was larger the larger the amount of KCl added and for a given concentration of KCl was also larger the smaller the initial concentration of AgNO/sub 3/. This shows that the Nernst law is not obeyed for AgNO/sub 3/ in the presence of Cl/sup -/ ion. (auth)|
|Learning Resource Type||Article|
|Publisher Department||Oak Ridge National Lab., Tenn.|
|Journal||Journal of Physical Chemistry|
|Organization||Oak Ridge National Lab., Tenn.|
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