Access Restriction

Author Oh, Sanghwa ♦ Shin, Won Sik ♦ Kim, Hong Tae
Source Paperity
Content type Text
Publisher Springer Berlin Heidelberg
File Format PDF ♦ HTM / HTML
Copyright Year ©2016
Subject Keyword Environment ♦ Environmental chemistry ♦ Ecotoxicology ♦ Environmental health ♦ Atmospheric protection/air quality control/air pollution ♦ Waste water technology / water pollution control / water management / aquatic pollution
Abstract Ibuprofen is well known as one of the most frequently detected pharmaceuticals and personal care products (PPCPs) in rivers. However, sorption of ibuprofen onto sediment has not been considered in spite of its high K ow (3.5). In this study, the effects of various environmental conditions such as pH (4, 5.3, and 7), the concentrations of dissolved organic matters (0 to 1.0 mM citrate and urea), salinity (0, 10, 20, and 30 part per thousand), and presence of other PPCP (salicylic acid) on ibuprofen sorption were investigated. Linear model mainly fitted the experimental data for analysis. The distribution coefficient (K d) in the linear model decreased from 6.76 at pH 4 to near zero at pH 7, indicating that neutral form of ibuprofen at pH below pKa (5.2) was easily sorbed onto the sediment whereas the sorption of anionic form at pH over pKa was not favorable. To investigate the effect of dissolved organic matters (DOMs) on ibuprofen sorption, citrate and urea were used as DOMs. As citrate concentration increased, the K d value decreased but urea did not interrupt the ibuprofen sorption. Citrate has three carboxyl functional groups which can attach easily ibuprofen and hinder its sorption onto sediment. Salinity also affected ibuprofen sorption due to decrease of the solubility of ibuprofen as salinity increased. In competitive sorption experiment, the addition of salicylic acid also led to enhance ibuprofen sorption. Conclusively, ibuprofen can be more easily sorbed onto the acidified sediments of river downstream, especially estuaries or near-shore environment with low DOM concentration.
ISSN 09441344
Learning Resource Type Article
Publisher Date 2016-11-01
e-ISSN 16147499
Journal Environmental Science and Pollution Research
Volume Number 23
Issue Number 22