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Author Zhou, Lin ♦ Zhou, Lushan ♦ Yang, Mingmei ♦ Wu, Di ♦ Liao, Lei ♦ Yan, Kai ♦ Xie, Qin ♦ Liu, Zhirong ♦ Peng, Hailin ♦ Liu, Zhongfan
Source World Health Organization (WHO)-Global Index Medicus
Content type Text
Publisher Wiley-VCH
File Format HTM / HTML
Language English
Difficulty Level Medium
Subject Domain (in DDC) Technology ♦ Medicine & health
Abstract Graphene, a two-dimensional giant-molecule of sp(2) -bonded carbon atoms, provides a perfect platform for studying free radical reaction chemistry in two-dimensions, which holds promise to control the chemical functionality of graphene. Free-radical photochlorination of graphene is used as an example to investigate the thickness, stacking order, and single- and double-side dependent reactivity in graphene. Anomalously low reactivity is observed in the photochlorination of AB-stacked bilayer graphene in comparison with that of few-layer graphene. Double-sided chlorination of graphene shows higher reactivity and chlorine coverage than single-sided reaction. It is also experimentally and theoretically demonstrated that chlorine free radicals at low coverage prefer to form a stable charge-transfer complex with graphene, which highly enhances graphene's conductivity and simultaneously generates a pseudo-bandgap through noninvasive doping. Moreover, the initial accumulation of chlorine radicals is considered as the rate-determining step of photochlorination of graphene.
Description Author Affiliation: Zhou L ( Center for Nanochemistry, Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China.)
ISSN 16136810
Educational Role Student ♦ Teacher
Age Range above 22 year
Educational Use Reading ♦ Research ♦ Self Learning
Interactivity Type Expositive
Education Level UG and PG
Learning Resource Type Article
Publisher Date 2013-04-22
Publisher Place Germany
e-ISSN 16136829
Journal Small
Volume Number 9
Issue Number 8


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Source: WHO-Global Index Medicus