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Author Tilset, M.
Sponsorship USDOE
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Language English
Subject Keyword CHEMISTRY ♦ CHROMIUM COMPLEXES ♦ OXIDATION ♦ RADICALS ♦ HYDRIDES ♦ ORGANOMETALLIC COMPOUNDS ♦ THERMODYNAMIC PROPERTIES
Abstract The authors used thermodynamic data extracted from electrochemical studies for estimations of M-H bond dissociation energies (BDEs) in solution. Here, estimates of M-H BDEs in metal hydride cation radicals are made and the relative yields of homolytic and heterolytic cleavage of M-H resulting from 1e{sup {minus}} oxidation processes are considered. 18 refs., 2 figs., 2 tabs.
ISSN 00027863
Educational Use Research
Learning Resource Type Article
Publisher Date 1992-03-25
Publisher Place United States
Journal Journal of the American Chemical Society
Volume Number 114
Issue Number 7


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