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Author Fei, Beatrice Wong Chui ♦ Hanifah, Sharina Abu ♦ Ahmad, Azizan ♦ Hassan, Nur Hasyareeda
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Language English
Subject Keyword INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ♦ AMORPHOUS STATE ♦ CROSS-LINKING ♦ ELECTROLYTES ♦ FILMS ♦ FOURIER TRANSFORMATION ♦ IMIDAZOLES ♦ IMIDES ♦ INFRARED SPECTRA ♦ IONIC CONDUCTIVITY ♦ METHACRYLATES ♦ MONOMERS ♦ ORGANIC POLYMERS ♦ SALTS ♦ X-RAY DIFFRACTION
Abstract Polymer electrolytes based on crosslinked poly(glycidyl methacrylate) as polymer host and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BmimTFSI) as incorporated salt were prepared by in-situ photopolymerization technique. The complexes with different mass ratio of glycidyl methacrylate (GMA) monomer to BmimTFSI were investigated. The ionic conductivity of the polymer electrolyte was increased and reach the highest value of 7.50 × 10{sup −4} S cm{sup −1} at the ratio of 3:7 (GMA: BmimTFSI). The interaction between the polymer host and ionic liquid was proved by Attenuated Total Reflectance-Fourier Transformation Infra-Red Spectroscopy (ATR-FTIR). Meanwhile, the X-ray diffraction analysis shows the amorphousity of the polymer electrolyte film increase with the ionic liquid ratio.
ISSN 0094243X
Educational Use Research
Learning Resource Type Article
Publisher Date 2015-09-25
Publisher Place United States
Volume Number 1678
Issue Number 1


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