|Author||Kane, S. M. ♦ Gland, J. L. ♦ Huntley, D. R.|
|Source||United States Department of Energy Office of Scientific and Technical Information|
|Subject Keyword||MATERIALS SCIENCE ♦ CHEMISTRY ♦ TOLUENE ♦ DESORPTION ♦ THIOLS ♦ CHEMICAL REACTIONS ♦ CATALYSIS ♦ CATALYSTS ♦ NICKEL ♦ SURFACES ♦ MASS SPECTRA ♦ ORGANIC SULFUR COMPOUNDS|
|Abstract||We report our observation of interspecies carbon-carbon bond formation during the reaction of coadsorbed methanethiol and benzenethiol on the Ni(III) surface. Toluene formation has been detected between 250 and 320 K in addition to methane and benzene, the hydrogenolysis products. Increased concentrations of benzenethiolate and methanethiolate, the surface intermediates, increase the amount of toluene formed. Water formation below the toluene formation temperature decreases surface hydrogen, causing toluene yield to increase substantially compared to methane and benzene yield. Toluene increases up to a factor of 20 were observed for high coadsorbed coverages. Together, these results clearly indicate that competition between hydrogen addition and alkylation controls toluene formation. 28 refs., 3 figs.|
|Learning Resource Type||Article|
|Publisher Place||United States|
|Journal||Journal of the American Chemical Society|
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