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Author Cade, N. I. ♦ Culfaz, F. ♦ Eligal, L. ♦ Ritman-Meer, T. ♦ Huang, F-M ♦ Festy, F. ♦ Richards, D.
Source arXiv.org
Content type Text
File Format PDF
Date of Submission 2008-04-25
Language English
Subject Domain (in DDC) Computer science, information & general works ♦ Natural sciences & mathematics ♦ Physics
Subject Keyword Condensed Matter - Other Condensed Matter ♦ Condensed Matter - Materials Science ♦ physics:cond-mat
Abstract We report modifications to the optical properties of fluorophores in the vicinity of noble metal nanotips. The fluorescence from small clusters of quantum dots has been imaged using an apertureless scanning near-field optical microscope. When a sharp gold tip is brought close to the sample surface, a strong distance-dependent enhancement of the quantum dot fluorescence is observed, leading to a simultaneous increase in optical resolution. These results are consistent with simulations of the electric field and fluorescence enhancement near plasmonic nanostructures. Highly ordered periodic arrays of silver nanotips have been fabricated by nanosphere lithography. Using fluorescence lifetime imaging microscopy, we have created high resolution spatial maps of the lifetime components of vicinal fluorophores; these show an order of magnitude increase in decay rate from a localized volume around the nanotips, resulting in a commensurate enhancement in the fluorescence emission intensity. Spatial maps of the Raman scattering signal from molecules on the nanotips shows an enhancement of more than 5 orders of magnitude.
Educational Use Research
Learning Resource Type Article


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