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Author Murphy, V. J. ♦ Hascall, T. ♦ Chen, J. Y. ♦ Parkin, G.
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Language English
Subject Keyword CHEMISTRY ♦ MOLYBDENUM COMPLEXES ♦ SYNTHESIS ♦ STRUCTURAL CHEMICAL ANALYSIS ♦ CHEMICAL BONDS ♦ HYDROGEN ♦ MOLECULAR STRUCTURE ♦ ORGANIC FLUORINE COMPOUNDS ♦ FLUORIDES
Abstract In this paper, we describe the synthesis and structural characterization of the bifluoride complex Mo(PMe{sub 3}){sub 4}H{sub 2} F(FHF). In summary, structural and spectroscopic data suggest that the hydrogen-bonding interaction in the bifluoride complex Mo(PMe{sub 3}){sub 4}H{sub 2}F(FHF) may be regarded as `strong`; however, as would be expected on simple electrostatic grounds, the interaction between the covalently bound Mo-F moiety and H-F is weaker than that between F{sup -} and H-F. 25 refs., 1 fig.
ISSN 00027863
Educational Use Research
Learning Resource Type Article
Publisher Date 1996-08-07
Publisher Place United States
Journal Journal of the American Chemical Society
Volume Number 118
Issue Number 31


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