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Author Cubicciotti, D.
Sponsorship USDOE
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Language English
Subject Keyword CHEMISTRY ♦ BISMUTH ♦ BISMUTH IODIDES ♦ ENTHALPY ♦ MEASURED VALUES ♦ POLYMERS ♦ PRESSURE ♦ TEMPERATURE ♦ TRANSPIRATION METHOD ♦ VAPORS
Abstract S>The equilibrium 2/3 Bi(l) + 1/3 BiI/sub 3/(g) = BiI(g) was studied by a transpirat ion technique over the temperature range 545 to 735 deg and the pressure range 0.1 to 50 mm. The enthalpy change for the reaction was 21 kcal and the standard entropy 16 eu at mid-temperature. An excess pressure of reduced Bi species in the higher pressure range was interpreted as due to the formation of a polymer, Bi/sub n/I/sub n/. (auth)
ISSN 00223654
Educational Use Research
Learning Resource Type Article
Publisher Date 1961-03-01
Publisher Department Stanford Research Inst., Menlo Park, Calif.
Journal Journal of Physical Chemistry
Volume Number 65
Organization Stanford Research Inst., Menlo Park, Calif.


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