|Author||Zeck, O. F. ♦ Su, Y. Y. ♦ Gennaro, G. P. ♦ Tang, Y. N.|
|Source||United States Department of Energy Office of Scientific and Technical Information|
|Publisher||American Chemical Society (ACS)|
|Subject Keyword||RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY ♦ SILANES- HOT ATOM CHEMISTRY ♦ SILICON 31- HOT ATOM CHEMISTRY ♦ CYCLOALKENES ♦ NITRIC OXIDE|
|Abstract||Silylene-<sup>31</sup>Si adds to 1,3-butadiene to give silacyclopent-3-ene- <sup>31</sup>Si. Studies using nitric oxide as a scavenger demonstrate that the reacting silylene is present as 80 percent triplet and 20 percent singlet, while studies using neon as a moderator prove that the ground electronic state of silylene is a singlet.|
|Learning Resource Type||Article|
|Publisher Department||Texas A and M Univ., College Station|
|Publisher Place||United States|
|Journal||Journal of the American Chemical Society|
|Organization||Texas A and M Univ., College Station|
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