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Author Zeck, O. F. ♦ Su, Y. Y. ♦ Gennaro, G. P. ♦ Tang, Y. N.
Sponsorship USDOE
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Publisher American Chemical Society (ACS)
Language English
Subject Keyword RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY ♦ SILANES- HOT ATOM CHEMISTRY ♦ SILICON 31- HOT ATOM CHEMISTRY ♦ CYCLOALKENES ♦ NITRIC OXIDE
Abstract Silylene-<sup>31</sup>Si adds to 1,3-butadiene to give silacyclopent-3-ene- <sup>31</sup>Si. Studies using nitric oxide as a scavenger demonstrate that the reacting silylene is present as 80 percent triplet and 20 percent singlet, while studies using neon as a moderator prove that the ground electronic state of silylene is a singlet.
ISSN 00027863
Educational Use Research
Learning Resource Type Article
Publisher Date 1974-09-01
Publisher Department Texas A and M Univ., College Station
Publisher Place United States
Journal Journal of the American Chemical Society
Volume Number 96
Issue Number 19
Organization Texas A and M Univ., College Station


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