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Author Tuazon, E. C. ♦ Mac Leod, H. ♦ Atkinson, R. ♦ Carter, W. P. L.
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Language English
Subject Keyword ENVIRONMENTAL SCIENCES ♦ BENZENE ♦ SYNTHESIS ♦ NITRIC OXIDE ♦ OXIDATION ♦ PHOTOCHEMISTRY ♦ TOLUENE ♦ XYLENES ♦ ABSORPTION SPECTROSCOPY ♦ AROMATICS ♦ ATMOSPHERIC CHEMISTRY ♦ CARBONYLS ♦ GAS CHROMATOGRAPHY ♦ HYDROCARBONS ♦ ALKYLATED AROMATICS ♦ CHALCOGENIDES ♦ CHEMICAL REACTIONS ♦ CHEMISTRY ♦ CHROMATOGRAPHY ♦ NITROGEN COMPOUNDS ♦ NITROGEN OXIDES ♦ ORGANIC COMPOUNDS ♦ OXIDES ♦ OXYGEN COMPOUNDS ♦ SEPARATION PROCESSES ♦ SPECTROSCOPY ♦ Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989)
Abstract The yields of the ring cleavage products glyoxal, methylglyoxal, and biacetyl from the reactions of OH radicals with benzene, toluene, o-, m-, and p-xylene, and 1,2,3-, 1,2,4-, and 1,3,5-trimethylbenzene in the presence of parts per million concentrations of NO have been determined in 1 atm of air at 298 +/- 2 K using in situ long-path-length Fourier transform infrared absorption spectroscopy and differential optical absorption spectroscopy with supplementary gas chromatographic analyses. These data are important inputs to chemical models of the NO/sub x/-air photoxidations of these aromatic hydrocarbons. 25 references, 3 figures, 1 table.
Educational Use Research
Learning Resource Type Article
Publisher Date 1986-04-01
Publisher Place United States
Journal Environ. Sci. Technol.
Volume Number 20
Issue Number 4
Organization Univ. of California, Riverside


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