Thumbnail
Access Restriction
Open

Author Sakodynskaya, I. K.
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Language English
Subject Keyword INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ♦ ATOMIC AND MOLECULAR PHYSICS ♦ AMMONIUM COMPLEXES ♦ NMR SPECTRA ♦ PALLADIUM COMPLEXES ♦ ACETIC ACID ♦ AMINES ♦ CARBON 13 ♦ CHEMICAL REACTION KINETICS ♦ CHEMICAL SHIFT ♦ COUPLING CONSTANTS ♦ DEUTERIUM COMPOUNDS ♦ DMSO ♦ HYDROGEN 1 ♦ INFRARED SPECTRA ♦ J-J COUPLING ♦ LITHIUM CHLORIDES ♦ MOLECULAR STRUCTURE ♦ QUATERNARY COMPOUNDS ♦ STRUCTURAL CHEMICAL ANALYSIS ♦ SYNTHESIS ♦ ALKALI METAL COMPOUNDS ♦ AMMONIUM COMPOUNDS ♦ CARBON ISOTOPES ♦ CARBOXYLIC ACIDS ♦ CHLORIDES ♦ CHLORINE COMPOUNDS ♦ COMPLEXES ♦ COUPLING ♦ EVEN-ODD NUCLEI ♦ HALIDES ♦ HALOGEN COMPOUNDS ♦ HYDROGEN COMPOUNDS ♦ HYDROGEN ISOTOPES ♦ INTERMEDIATE COUPLING ♦ ISOTOPES ♦ KINETICS ♦ LIGHT NUCLEI ♦ LITHIUM COMPOUNDS ♦ LITHIUM HALIDES ♦ MONOCARBOXYLIC ACIDS ♦ NUCLEI ♦ ODD-EVEN NUCLEI ♦ ORGANIC ACIDS ♦ ORGANIC COMPOUNDS ♦ ORGANIC SULFUR COMPOUNDS ♦ REACTION KINETICS ♦ SPECTRA ♦ STABLE ISOTOPES ♦ SULFOXIDES ♦ TRANSITION ELEMENT COMPLEXES 400201* -- Chemical & Physicochemical Properties ♦ Atomic, Molecular & Chemical PhysicsAtomic & Molecular Properties & Theory
Abstract The authors determine that dimeric cyclopalladated N,N-dialkylbenzylamines react with LiCl in acetic acid with the formation not of the anionic monomeric complexes reported earlier but of dialkylbenzylammonium chloropalladates. The presence of a nonmetallated ring in these complexes is evidenced unambiguously by the C 13 NMR spectra. When the salts obtained are dissolved in methanol fast o-palladation occurs with the regeneration of the original dimeric palladocycles. Chemical shifts and spin-spin coupling constants are analyzed.
Educational Use Research
Learning Resource Type Article
Publisher Date 1987-10-10
Publisher Place United States
Journal J. Gen. Chem. USSR
Volume Number 57
Issue Number 4
Organization M. V. Lomonosov Moscow State Univ. (USSR)


Open content in new tab

   Open content in new tab