|Author||Sakodynskaya, I. K.|
|Source||United States Department of Energy Office of Scientific and Technical Information|
|Subject Keyword||INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ♦ ATOMIC AND MOLECULAR PHYSICS ♦ AMMONIUM COMPLEXES ♦ NMR SPECTRA ♦ PALLADIUM COMPLEXES ♦ ACETIC ACID ♦ AMINES ♦ CARBON 13 ♦ CHEMICAL REACTION KINETICS ♦ CHEMICAL SHIFT ♦ COUPLING CONSTANTS ♦ DEUTERIUM COMPOUNDS ♦ DMSO ♦ HYDROGEN 1 ♦ INFRARED SPECTRA ♦ J-J COUPLING ♦ LITHIUM CHLORIDES ♦ MOLECULAR STRUCTURE ♦ QUATERNARY COMPOUNDS ♦ STRUCTURAL CHEMICAL ANALYSIS ♦ SYNTHESIS ♦ ALKALI METAL COMPOUNDS ♦ AMMONIUM COMPOUNDS ♦ CARBON ISOTOPES ♦ CARBOXYLIC ACIDS ♦ CHLORIDES ♦ CHLORINE COMPOUNDS ♦ COMPLEXES ♦ COUPLING ♦ EVEN-ODD NUCLEI ♦ HALIDES ♦ HALOGEN COMPOUNDS ♦ HYDROGEN COMPOUNDS ♦ HYDROGEN ISOTOPES ♦ INTERMEDIATE COUPLING ♦ ISOTOPES ♦ KINETICS ♦ LIGHT NUCLEI ♦ LITHIUM COMPOUNDS ♦ LITHIUM HALIDES ♦ MONOCARBOXYLIC ACIDS ♦ NUCLEI ♦ ODD-EVEN NUCLEI ♦ ORGANIC ACIDS ♦ ORGANIC COMPOUNDS ♦ ORGANIC SULFUR COMPOUNDS ♦ REACTION KINETICS ♦ SPECTRA ♦ STABLE ISOTOPES ♦ SULFOXIDES ♦ TRANSITION ELEMENT COMPLEXES 400201* -- Chemical & Physicochemical Properties ♦ Atomic, Molecular & Chemical PhysicsAtomic & Molecular Properties & Theory|
|Abstract||The authors determine that dimeric cyclopalladated N,N-dialkylbenzylamines react with LiCl in acetic acid with the formation not of the anionic monomeric complexes reported earlier but of dialkylbenzylammonium chloropalladates. The presence of a nonmetallated ring in these complexes is evidenced unambiguously by the C 13 NMR spectra. When the salts obtained are dissolved in methanol fast o-palladation occurs with the regeneration of the original dimeric palladocycles. Chemical shifts and spin-spin coupling constants are analyzed.|
|Learning Resource Type||Article|
|Publisher Place||United States|
|Journal||J. Gen. Chem. USSR|
|Organization||M. V. Lomonosov Moscow State Univ. (USSR)|
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