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Author Lee, E. K. C. ♦ Tang, Y. N. ♦ Rowland, F. S.
Source United States Department of Energy Office of Scientific and Technical Information
Content type Text
Language English
Subject Keyword CHEMISTRY ♦ ATOMS ♦ CARBON DIOXIDE ♦ CARBON MONOXIDE ♦ CARBONYLS ♦ CHEMICAL REACTIONS ♦ CHLORINE 35 ♦ CHROMATOGRAPHY ♦ EFFICIENCY ♦ ENERGY ♦ ENERGY RANGE ♦ ETHYL RADICALS ♦ EXCITATION ♦ FREONS ♦ GASES ♦ IRRADIATION ♦ ISOTOPE EFFECTS ♦ LABELLED COMPOUNDS ♦ MEASURED VALUES ♦ MIXING ♦ NEUTRON BEAMS ♦ NUCLEAR REACTIONS ♦ OPERATION ♦ ORGANIC CHLORINE COMPOUNDS ♦ ORGANIC FLUORINE COMPOUNDS ♦ ORGANIC SULFUR COMPOUNDS ♦ OXYGEN ♦ PERFORMANCE ♦ PREPARATION ♦ PROTONS ♦ RADIOCHEMISTRY ♦ RADIOISOTOPES ♦ RECOILS ♦ SEPARATION PROCESSES ♦ SULFIDES ♦ SULFUR ♦ SULFUR 35 ♦ USES ♦ VARIATIONS
Abstract Recoil S/sup 35/ atoms from the nuclear reaction Cl/sup 35/(n,p)S/sup 35/ were produced in CO- C/sub 2/F/sub 4/Cl/sub 2/ and CO/sub 2/- C/sub 2/F/sub 4/Cl /sub 2/ gaseous mixtures. Carbonyl sulfide (OCS/sup 35/) was isolated from each system by radio-gas chromatography. The reaction with CO/sub 2/ is probably initiated by an energetic species and accounts for about 2% of the total S/sup 35/ . The reaction with CO is probably a scavenger reaction for thermal S/sup 35/ atoms and accounts for as much as an estimated 85% of the total S/sup 35/ production. The yield is greatly reduced in the simultaneous presence of O/sub 2/ and CO. The very high yield of OCS/sup 35/ from CO systems indicates a convenient synthetic method of preparation for this labeled molecule. (auth) radiated polymers were extended to study the effects of
ISSN 00223654
Educational Use Research
Learning Resource Type Article
Publisher Date 1964-02-01
Publisher Department Univ. of Kansas, Lawrence
Journal Journal of Physical Chemistry
Volume Number 68
Organization Univ. of Kansas, Lawrence


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