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Author Chang, E. ♦ Chen, C. H.
Source SpringerLink
Content type Text
Publisher Springer-Verlag
File Format PDF
Copyright Year ©1997
Language English
Subject Domain (in DDC) Natural sciences & mathematics ♦ Chemistry & allied sciences
Subject Keyword brazing ♦ diffusion ♦ electrochemical property ♦ microstructure ♦ titanium ♦ Characterization and Evaluation of Materials ♦ Materials Science ♦ Tribology, Corrosion and Coatings ♦ Quality Control, Reliability, Safety and Risk ♦ Engineering Design
Abstract Filler metal of a low-melting-point (917 °C) Ti-21Ni-14Cu was brazed onto the substrate of Ti-6Al-4V alloy at 960 °C for 2,4, and 8 h to investigate the microstructural evolution and electrochemical characteristics of the brazed metal as a function of the period of brazing time. Optical microscopy, scanning and transmission electron microscopy, and x-ray diffractometry were used to characterize the microstructure and phase of the brazed metal; also, the potentiostat was used for corrosion study. Experimental results indicate that diffusion of copper and nickel from the filler metal into the equiaxed a plus intergranular β structure of Ti-6Al-4V substrate causes the lamellar Widmanstätten structure to form. The intermetallic Ti$_{2}$Ni phase existing in the prior filler metal diminishes, while the Ti$_{2}$Cu phase can be identified for the metal brazed at 960 °C for 2 h, but the latter phase decreases with time. Advantage might be taken from the evidence of faster diffusion of nickel than copper along the β phase to the substrate. In deaerated Hank’s solution, corrosion potential, corrosion current density, and critical potential for active-to-passive transition decrease while the passivation range broadens with the period of brazing time. However, all the brazed metals, immersed for different periods in oxygen-saturated Hank’s solution, show similar corrosion behavior, irrespective of the brazing time.
ISSN 10599495
Age Range 18 to 22 years ♦ above 22 year
Educational Use Research
Education Level UG and PG
Learning Resource Type Article
Publisher Date 1997-01-01
Publisher Place New York
e-ISSN 15441024
Journal Journal of Materials Engineering and Performance
Volume Number 6
Issue Number 6
Page Count 7
Starting Page 797
Ending Page 803

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Source: SpringerLink