Access Restriction

Author Wei, Yun ♦ Qiu, Longhui ♦ Owen, Craig ♦ Lai, Edward P. C.
Source SpringerLink
Content type Text
Publisher Springer-Verlag
File Format PDF
Copyright Year ©2007
Language English
Subject Domain (in DDC) Natural sciences & mathematics ♦ Chemistry & allied sciences
Subject Keyword Quantum dots ♦ Carbon nanotubes ♦ Polypyrrole ♦ Ochratoxin A ♦ Molecularly imprinted polymer ♦ Micro-solid phase preconcentration ♦ Automated analysis ♦ Engineering ♦ Chemistry/Food Science ♦ Food Science
Abstract Nanometer-sized semiconductor quantum dots (QDs with CdSe core and ZnS shell) and carbon nanotubes (CNTs with multi-walls) were encapsulated inside a stainless steel syringe needle by electrodeposition of polypyrrole (PPy). By cross-linking the PPy with ethylene glycol dimethacrylate (EGDMA) in the presence of ochratoxin A (OTA) as a template, molecularly imprinted polypyrrole (MIPPy) was formed on the nano-hybrid structure at an increased specific surface area. The MIPPy/CNTs/QDs-modified needle was readily adapted in an autosampler for micro-solid phase preconcentration (μSPP) of OTA from a red wine sample. After pulsed elution (PE) with 2% triethylamine (TEA), the OTA was determined by high performance liquid chromatography (HPLC) with fluorescence detection (FD). In comparison with MIPPy/CNTs, this new nano-hybrid structure of MIPPy/CNTs/QDs significantly improved the % recovery of OTA. The method, MIPPy/CNTs/QDs-μSPP-HPLC-FD, demonstrated that the MIPPy was truly a molecularly imprinted polymer (MIP) with specific recognition for OTA. All red wine matrix components could be differentially washed out, prior to accurate determination of the strongly bound OTA.
ISSN 19327587
Age Range 18 to 22 years ♦ above 22 year
Educational Use Research
Education Level UG and PG
Learning Resource Type Article
Publisher Date 2007-07-18
Publisher Place New York
e-ISSN 19329954
Journal Sensing and Instrumentation for Food Quality and Safety
Volume Number 1
Issue Number 3
Page Count 9
Starting Page 133
Ending Page 141

Open content in new tab

   Open content in new tab
Source: SpringerLink