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Subject Domain (in DDC) Computer science, information & general works ♦ Data processing & computer science
Subject Keyword Redox Property ♦ Electronic Characteristic ♦ Camphor Derived Ligand ♦ Ligand Influence ♦ Camphor Specie ♦ Direct Positive Correlation ♦ Redox Potential ♦ Cyclic Voltammetry ♦ Camphor Skeleton ♦ Potential Value ♦ Cu Camphor Complex ♦ Cathodic Process ♦ Electrochemical Data ♦ P-hammett Parameter ♦ Metal Drive ♦ Several Camphor-type
Abstract The electrochemical data obtained by cyclic voltammetry on several camphor-type (A, B and C) ligands and derived complexes are revised. A direct positive correlation is established between the redox potentials (anodic or cathodic) of the camphor species and the σp-Hammett parameter of the R group on the camphor skeleton. A study of the effect of the ligand on the redox properties of some Pd, Pt or Cu camphor complexes shows that the ligands influence either the anodic or cathodic processes but the characteristics of the metal drive the potential values.
Educational Role Student ♦ Teacher
Age Range above 22 year
Educational Use Research
Education Level UG and PG ♦ Career/Technical Study
Publisher Date 2003-01-01